21286-78-2

Upstream product

• 67-56-1 methanol 
• 1199-01-5 2-phenylazlactone 
• 1205-08-9 methyl hippurate 
• 19791-95-8 α-hydroxyhippuric acid 
• 56538-62-6 N-benzoyl-α-benzylthioglycine methyl ester 
• 110339-41-8 methyl (acetyloxy)(benzoylamino)acetate 
• 55-21-0 benzamide 
• 98-88-4 benzoyl chloride 
• 20989-42-8 N-benzoylserine methyl ester 

Downstream Products

• 58178-31-7 2-Benzamido-4-phenyl-3-butenoic acid 
• 65427-66-9 methyl 2-benzamido-4-phenylbutanoate 
• 58178-26-0 (Z)-2-Benzoylamino-4-phenyl-but-3-enoic acid methyl ester 
• 58178-32-8 (2RS)-1-methyl-1-benzoylamino-4-dimethoxybutanoic acid 
• 67809-42-1 N-Benzoyl-β,β-dibenzoyl-alanin-methylester 
• 58178-30-6 2-Benzamido-4-phenyl-3-pentenoic acid 
• 120341-30-2 methyl 2-benzamido-2-(diphenoxyphosphoryl)acetate 
• 56538-62-6 N-benzoyl-α-benzylthioglycine methyl ester 
• 106294-26-2 Benzoylamino-(2-oxo-cyclohexyl)-acetic acid methyl ester 
• 1205-08-9 methyl hippurate 
• 258505-90-7 (+/-)-dimethyl-2,3-dibenzamidobutanedioate 
• 144978-22-3 N-benzoyl-α-t-butylthioglycine methyl ester 
• 120341-29-9 Benzoylamino-(diisopropoxy-phosphoryl)-acetic acid methyl ester 
• 120811-95-2 Benzoylamino-p-tolylselanyl-acetic acid methyl ester 

Relevant academic research and scientific papers

The efficient direct synthesis of N,O-acetal compounds as key intermediates of discorhabdin A: Oxidative fragmentation reaction of α-amino acids or β-amino alcohols by using hypervalent iodine(III) reagents

Hypervalent iodine(III) reagents are readily available, easy to handle, and have a low toxicity and similar reactivities to those of heavy metal reagents, and hence they are used for various oxidative reactions. The oxidative cleavage of alkynes or carbon

Methods for the synthesis of dicarba bridges in organic compounds

The present invention relates to methods for forming dicarba bridges in organic compounds. This involves the use of a pair of complementary metathesisable groups on the organic compound, and subjecting the compound to cross-metathesis under microwave radiation conditions. In an alternative, the compounds contain a turn-inducing group between the pair of cross-metathesisable groups to facilitate the cross-metathesis.

Conotoxin analogues and methods for synthesis of intramolecular dicarba bridge-containing peptides

According to the present invention, there is provided a range of new conotoxin derivatives and methods for synthesizing these analogues and other intramolecular dicarba bridge-containing peptides, including dicarba-disulfide bridge-containing peptides.

Synthesis of unnatural amino acids from serine derivatives by β-fragmentation of primary alkoxyl radicals

(Chemical Equation Presented) The fragmentation of primary alkoxyl radicals has been scarcely used in synthesis since other competing processes (such as oxidation or hydrogen abstraction) usually predominate. However, when serine derivatives were used as

INDIRECT ELECTROCHEMICAL α-METHOXYLATION OF N-ACYL AND N-CARBOALKOXY α-AMINO ACID ESTERS AND APPLICATION AS CATIONIC GLYCINE EQUIVALENTS

Indirect electrochemical methoxylation of N-acyl and N-carboalkoxy α-amino acid esters in α-position to nitrogen is possible, if chloride is used as mediator.The course of the reaction depends upon the protecting group as well as upon the amino acid side-chain.Increased electron withdrawing effects of the protecting group are accelerating the reaction.On the other hand aliphatic side-chains are diminishing the reactivity.High chloride ion concentrations improve the current yields surprisingly strong.

FACILE SYNTHESIS OF α-PHOSPHORYLATED α-AMINO ACIDS

Various α-phosphorylated α-amino acid derivatives were synthesized conveniently by the reaction of methyl α-methoxyhippurate and methyl α-methoxy-N-benzyloxycarbonyl-glycinate with phosphites under the Lewis acid.Hydrolysis of (12) with TMSI gave 2-phosph