217-65-2Relevant articles and documents
Site-selective synthesis of functionalized dibenzo[: F, h] quinolines and their derivatives involving cyclic diaryliodonium salts via a decarboxylative annulation strategy
Yang, Shuai,Hua, Wenkai,Wu, Yanqi,Hu, Tao,Wang, Feng,Zhang, Xingxian,Zhang, Fengzhi
, p. 3239 - 3242 (2018)
Here we report a site-selective synthesis of functionalized dibenzo[f,h]quinolines and their derivatives, which could be used as OLED materials. The key step is the double cross coupling reaction between the 2-chloropyridinyl acids and the cyclic diaryliodonium salts, where the carboxylic acid was unprecedentedly employed as both a traceless directing group and a functional handle in a one-pot atom- and step-economical process.
Synthesis of Redox-Active Phenanthrene-Fused Heteroarenes by Palladium-Catalyzed C-H Annulation
Jang, Jin Hyeok,Ahn, Seongmo,Park, Soo Eun,Kim, Soeun,Byon, Hye Ryung,Joo, Jung Min
supporting information, p. 1280 - 1285 (2020/02/28)
Pd-catalyzed C-H annulation reactions of halo- and aryl-heteroarenes were developed using readily available o-bromobiaryls and o-dibromoaryls, respectively. A variety of five-membered heteroarenes rapidly provided the corresponding phenanthrene-fused heteroarenes, which led to the identification of phenanthro-pyrazole and thiazole as new, stable -2 V redox couples. The flexible syntheses and tunability of the redox potentials of these azole-fused phenanthrenes over a wide range are expected to facilitate their application as redox-active organic functional materials.
GREEN PHOSPHORESCENT IRIDIUM COMPLEXES, FABRICATION METHOD THEREOF AND ORGANIC LIGHT-EMITTING DIODES COMPRISING THE SAME
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, (2011/01/05)
A green phosphorescent iridium complex represented by Formula (I) is provided. In Formula (I), R1, R2 and R3 are, independently, hydrogen, halogen, substituted or non-substituted C1-6 alkyl, C1-6 alkoxy, cycloalkyl, substituted or non-substituted aryl, amino or heteroaryl, and L is a heterocyclic ring containing N—N or N—O ligand. The invention also provides a method for fabricating the green phosphorescent iridium complex and an organic light-emitting diode including the green phosphorescent iridium complex.