21819-66-9Relevant academic research and scientific papers
Multifunctional red phosphorescent bis-cyclometallated iridium complexes based on 2-phenyl-1,2,3-benzotriazole ligand and carbazolyl moieties
Malinauskas, Tadas,Daskeviciene, Maryte,Kazlauskas, Karolis,Su, Hai-Ching,Grazulevicius, Juozas Vidas,Jursenas, Saulius,Wu, Chung-Chih,Getautis, Vytautas
experimental part, p. 1852 - 1861 (2011/04/17)
Multifunctional phosphorescent bis-cyclometallated iridium(III) complexes based on the 2-phenyl-1,2,3-benzotriazole moiety and bearing branched hole-transporting carbazole fragments were synthesized. The isolated compounds were found to be amorphous and e
TREATMENT OF DUCHENNE MUSCULAR DYSTROPHY
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Page/Page column 28; 43, (2010/11/28)
There are disclosed compound of Formula (I) or (II) wherein A1, A2, A3, A4and A5, which may be the same or different, represent N or CR1, R9 represents - L -R3, in whi
APPLICATION OF FLUORESCENT TRIAZOLES TO ANALYTICAL CHEMISTRY. III. FLUORESCENCE CHARACTERISTICS OF 2-PHENYLBENZOTRIAZOLYL-5-AMINE DERIVATIVES AS FLUORESCENT PROBES
Narita, Shigeru,Kitagawa, Takayasu
, p. 1005 - 1008 (2007/10/02)
2-Phenylbenzotriazole derivatives with a COCH3 or NH2 group on the 2-phenyl ring were synthesized and found to be applicable as fluorescent hydrophobic probes.The fluorescence intensities of these compounds, which were intense in non-polar solvents, were dramatically quenched in polar solvents.In particular, 2-(4-acetylphenyl)-2H-benzotriazolyl-5-amine (7) showed a much higher ratio of the fluorescence intensity in the organic solvent to that in water (Fo/Fw) than 8-anilino-1-naphthalenesulfonate (ANS): The Fo/Fw values of 7 were 470 for dioxane and 440 for acetone, while those of ANS were 100 for dioxane and 90 for acetone.We modified compound 7 to obtain water-soluble probes for use in drug-protein binding studies and examined the interaction of these probes with human serum albumin (HSA).All the compounds, which were practically non-fluorescent in the buffer solution, bound to HSA and fluoresced.Keywords: 2-phenylbenzotriazolyl-5-amine; fluorescence characteristies; solvent effect; fluorescent probe; protein binding
SYNTHESIS OF 5-HYDROXY-4-NITROSOBENZOTRIAZOLES AND 6-HYDROXY-7-NITROSO-INDAZOLES AND THEIR SPLITTING INTO β-TRIAZOLYL- AND β-PYRAZOLYLACRYLIC ACIDS
Stankyavichyus, A. P.,Terent'ev, P. B.,Bolotin, V. A.,Lashin, V. V.,Rakhimi, I. M.
, p. 403 - 409 (2007/10/02)
5-Hydroxy-4-nitrosobenzotriazoles and 6-hydroxy-7-nitrosoindazoles were synthesized.By the action of benzenesulfonyl chloride in an alkaline medium, only 5-hydroxy-4-nitroso-2-phenyl-benzotriazole and 1-methyl-6-hydroxy-7-nitrosoindazole split into 5-carb
