119718-87-5Relevant articles and documents
Acetoxylation of arylacetonitriles using (diacetoxyiodo)benzene
Varella,Varvoglis
, p. 531 - 534 (1991)
The direct α-acetoxylation of some arylacetonitriles using (diacetoxyiodo)benzene in the presence of dibenzoyl peroxide provides O-acetylated mandelonitriles in good yields.
Ionic liquid [bmim]BF4 as an efficient and recyclable reaction medium for the synthesis of O-acetyl cyanohydrin via one-pot condensation of aldehyde, TMSCN, and Ac2O
Shen, Zhi-Liang,Ji, Shun-Jun
, p. 808 - 818 (2009)
Ionic liquid [bmim]BF4 has been demonstrated to be an efficient and environmentally friendly reaction medium as well as reaction promoter for the synthesis of O-acetyl cyanohydrin via one-pot condensation of aldehyde, TMSCN, and Ac2O without Lewis acid or
Asymmetric induction by helical poly(amino acid)s in cyanosilylation of aldehydes
Akagawa, Kengo,Kudo, Kazuaki
, p. 5981 - 5983,3 (2012)
It was first demonstrated that helical poly(amino acid)s have an ability to induce enantioselectivity in the cyanosilylation of aldehydes. The helicity of poly(amino acid)s and the N-terminal amino group were essential for the enantioinduction of the reaction.
Naturally occurring cyanohydrins, analogues and derivatives as potential insecticides
Peterson, Chris J.,Tsao, Rong,Coats, Joel R.
, p. 615 - 617 (2000)
Several naturally occurring cyanohydrins were tested for fumigation toxicity to two insect species, the house fly (Musca domestica L) and the lesser grain borer (Rhyzopertha dominica (F)). Synthetic analogues of these compounds were tested as well. Most of the cyanohydrins tested were more toxic as fumigants to M domestica and R dominica than chloropicrin; some compounds were nearly as toxic as dichlorvos. Naturally occurring cyanohydrins were among the most toxic tested. (C) 2000 Society of Chemical Industry.
Asymmetric cyanohydrin synthesis using heterobimetallic catalysts obtained from titanium and vanadium complexes of chiral and achiral salen ligands
Belokon, Yuri N.,Clegg, William,Harrington, Ross W.,Young, Carl,North, Michael
, p. 5287 - 5299 (2007)
Titanium(IV)(salen) and vanadium(V)(salen) complexes are both known to form catalysts for asymmetric cyanohydrin synthesis. When a mixture of titanium and vanadium complexes derived from the same or different salen ligands is used for the asymmetric addit
Constructing a triangular metallacycle with salen-Al and its application to a catalytic cyanosilylation reaction
Li, Bo,Li, Yang,Qiu, Huayu,Xu, Jun,Yin, Shouchun,Zhang, Jinjin,Zhang, Pengfei,Zhang, Yueyue
, p. 10399 - 10402 (2021/10/12)
A triangular metallosalen-based metallacycle was constructed in quantitative yield by the self-assembly of a 180° bis(pyridyl)salen-Al complex and a 60° diplatinum(ii) acceptor in a 1?:?1 stoichiometric ratio. This metallacycle was then successfully used to cyanosilylate a wide range of benzaldehydes with trimethylsilyl cyanide.
Synthesis of Imidazoles and Oxazoles via a Palladium-Catalyzed Decarboxylative Addition/Cyclization Reaction Sequence of Aromatic Carboxylic Acids with Functionalized Aliphatic Nitriles
Dai, Ling,Yu, Shuling,Lv, Ningning,Ye, Xuanzeng,Shao, Yinlin,Chen, Zhongyan,Chen, Jiuxi
supporting information, p. 5664 - 5668 (2021/08/01)
We herein report an efficient approach for the assembly of multiply substituted imidazoles and oxazoles in a single-step manner. These transformations are based on a decarboxylation addition and annulation of readily accessible aromatic carboxylic acids a
