221189-56-6Relevant articles and documents
Gold-facilitated '6-exo-dig' intramolecular cyclization of 2-[(2-nitrophenyl)ethynyl]phenylacetic acids: General access to 5H-benzo[b]carbazole-6,11-diones
Salas, Cristian O.,Reboredo, Francisco J.,Estevez, Juan C.,Tapia, Ricardo A.,Estevez, Ramon J.
scheme or table, p. 3107 - 3110 (2010/03/02)
The preliminary results of a regiospecific synthesis of (Z)-1 -(2-nitrobenzylidene)isochroman-3-ones by gold(I)-catalyzed cycloisomerization of phenylethynylacetic acids under mild conditions is described. These novel lactones proved to be suitable starti
Palladium-catalyzed synthesis of o-acetylbenzoic acids: A new, efficient general route to 2-hydroxy-3-phenyl-1,4-naphthoquinones and indolo[2,3-b]naphthalene-6,11-diones
Barcia, José C,Cruces, Jacobo,Estévez, Juan C,Estévez, Ramón J,Castedo, Luis
, p. 5141 - 5144 (2007/10/03)
We describe here a new, efficient general synthesis of o-acetylbenzoic acids by Heck palladium-catalyzed arylation of n-butyl vinyl ether with o-bromobenzoic acid esters and the use of these compounds as starting materials for the synthesis of 3-benzylideneisochroman-1,4-diones, which readily rearrange to 2-hydroxy-3-phenyl-1,4-naphthoquinones. The application of this strategy to the synthesis of indolo[2,3-b]naphthalene-6,11-diones is also described.
A simple synthesis of benzocarbazolequinones via o-nitroarylation of 2- hydroxy-1,4-naphthoquinones
Kobayashi, Kazuhiro,Taki, Tetsuya,Kawakita, Masataka,Uchida, Masaharu,Morikawa, Osamu,Konishi, Hisatoshi
, p. 349 - 354 (2007/10/03)
The reaction of 2-hydroxy-1,4-naphthoquinones (1a-c) with o- fluoronitrobenzenes (2a,b) in the presence of K2CO3 in DMSO at 100 °C gave 2-hydroxy-3-(2-nitroaryl)-1,4-naphthoquinones (3a-e) in moderate to fair yields, which in turn we