22136-92-1

Upstream product

• 67-56-1 methanol 
• 112-43-6 10-Undecen-1-ol 
• 112-47-0 1,10-Decanediol 
• 112-19-6 10-undecenyl acetate 
• 10028-15-6 ozone 
• 64-19-7 acetic acid 
• 56-23-5 tetrachloromethane 

Downstream Products

• 64437-44-1 (E)-10-Pentadecen-1-ol 
• 64437-42-9 (10Z)-10-pentadecen-1-ol 
• 1393110-59-2 10-((4-methoxybenzyl)oxy)decanal 
• 92210-94-1 10(Z)-pentadecen-1-yltriphenylphosphonium bromide 
• 53120-26-6 (3E, 13Z)-3,13-octadecadien-1-yl acetate 
• 53120-27-7 (3Z,13Z)-3,13-octadecadien-1-yl acetate 

Relevant academic research and scientific papers

Pd(II)-hydrotalcite-catalyzed oxidation of alcohols to aldehydes and ketones using atmospheric pressure of air

A heterogenized Pd catalyst, Pd(II)-hydrotalcite (palladium(II) acetate-pyridine supported by hydrotalcite) catalyzes the aerobic oxidation in toluene of a variety of primary and secondary alcohols into the corresponding aldehydes and ketones in high yields using atmospheric pressure of air as a sole oxidant under mild conditions. This catalyst is also effective for the oxidation of allylic alcohols, especially such as geraniol and nerol, without any isomerization of an alkenic part. The catalyst can be easily prepared from all commercially available reagents and reused several times.

Bifunctional compounds from reaction of alkoxy hydroperoxides with metal salts

Alkoxy hydroperoxides, obtained by ozonizing olefins in alcoholic solution, were treated with ferrous sulfate. C-C bond scission and radical formation was followed by dimerization of the radicals formed. Ozonides reacted similarly. Acyclic and cyclic olefins, including a cyclic enol ether, gave rise to a range of α,ω-disubstituted products in modest yields. By using ferric chloride, ω-chloro esters were obtained from the alkoxy hydroperoxides derived from olefinic esters.