22198-57-8

Basic information

• Product Name: 2-Propanone, 1-(acetyloxy)-3-(phenylthio)-
• CAS NO: 22198-57-8
• Molecular Formula: C11H12O3S
• Molecular Weight: 224.28
• Mol File: 22198-57-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2-Propanone, 1-(acetyloxy)-3-(phenylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propanone, 1-(acetyloxy)-3-(phenylthio)-(22198-57-8)
• EPA Substance Registry System: 2-Propanone, 1-(acetyloxy)-3-(phenylthio)-(22198-57-8)

Safety Data

• Hazardous Substances Data: 22198-57-8(Hazardous Substances Data)

Upstream product

• 23533-56-4 1-diazo-3-phenylthiopropan-2-one 
• 7031-27-8 (phenylthio)acetic acid chloride 
• 22198-54-5 1-chloro-3-phenylsulfanylpropan-2-one 
• 64-19-7 acetic acid 
• 69753-43-1 1-chloro-1-phenylthio-2-propanone 
• 127-08-2 potassium acetate 
• 127-09-3 sodium acetate 
• 108-98-5 thiophenol 
• 534-07-6 1,3-Dichloroacetone 

Downstream Products

• 97798-47-5 1-hydroxy-3-phenylthio-2-propanone 
• 110210-93-0 2-hydroxy-3-phenylthiopropyl acetate 
• 110210-94-1 1-hydroxymethyl-2-phenylthioethyl acetate 
• 159002-92-3 Acetic acid 2-hydroxy-2-phenylsulfanylmethyl-pent-4-enyl ester 
• 159099-54-4 2-Phenylsulfanylmethyl-pent-4-ene-1,2-diol 
• 159002-93-4 1-(4-Methoxy-phenyl)-2-phenylsulfanylmethyl-pent-4-en-2-ol 
• 159099-53-3 2-Allyl-2-phenylsulfanylmethyl-oxirane 
• 97798-50-0 (S)-1,2-epoxy-3-(phenylthio)propane 
• 67210-33-7 (S)-(+)-1-(benzenesulfanyl)-2-butanol 
• 97798-48-6 (S)-(2,3-dihydroxypropyl) phenyl sulfide 
• 97859-56-8 (S)-1-Phenylsulfanyl-tridecan-2-ol 
• 97798-51-1 (S)-5-Phenyl-1-phenylsulfanyl-pentan-2-ol 
• 97798-49-7 3-phenylthio-2-hydroxy-1-tosyloxypropane 

Relevant articles and documents

OPTICALLY PURE (S)-3-PHENYLTHIO-1,2-PROPANEDIOL: SYNTHESIS BY THE YEAST REDUCTION AND USE AS A PRECURSOR OF BOTH ENANTIOMERS OF SECONDARY ALCOHOLS

Optically pure (S)-3-phenylthio-1,2-propanediol was obtained by the enantioselective reduction of 1-hydroxy-3-phenylthio-2-propanone with the Baker's yeast, and was found to be a convenient precursor for both enantiomers of secondary alcohols, which was d

NUCLEOPHILIC SUBSTITUTION OF α-HALO KETONES. XXI. STRUCTURE-REACTIVITY RELATIONSHIPS IN THE ACETOLYSIS OF 3-SUBSTITUTED 1-CHLORO-3-PHENYLTHIO-2-PROPANONES

The acetolyses of α-chloro ketones 1a-d have been re-investigated under standard conditions and compared with those of the corresponding isomeric substrates 2a-d.It has been shown that participation by the neighbouring phenylthio group, involving a 1-3 shift of the latter, does occur in part even in the case of 1d, while it is the only process in the case of 1e.A few structure-reactivity relationships in the two series of substrates are discussed.