22233-90-5

Basic information

• Product Name: Benzene, [(1,1-dimethylethyl)seleno]-
• Synonyms: BHLYTKXNEOBHAC-UHFFFAOYSA;Phenyl-tert.-butylselenid;t-butyl phenyl selenide;phenyl tert butyl selenide;tert-butyl phenyl selenide
• CAS NO: 22233-90-5
• Molecular Formula: C10H14Se
• Molecular Weight: 213.181
• Mol File: 22233-90-5.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: Benzene, [(1,1-dimethylethyl)seleno]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(1,1-dimethylethyl)seleno]-(22233-90-5)
• EPA Substance Registry System: Benzene, [(1,1-dimethylethyl)seleno]-(22233-90-5)

Safety Data

• Hazardous Substances Data: 22233-90-5(Hazardous Substances Data)

Upstream product

• 17697-12-0 benzeneseleninic anhydride 
• 37426-22-5 cyclohexanone tert-butylhydrazone 
• 507-20-0 tertiary butyl chloride 
• 1666-13-3 diphenyl diselenide 
• 645-96-5 Benzeneselenol 
• 115-11-7 isobutene 
• 151484-28-5 1,1-dimethylethyl diphenylphosphinite 
• 5707-04-0 Phenylselenyl chloride 
• 594-19-4 tert.-butyl lithium 
• 23974-72-3 sodium phenylselenide 
• 558-17-8 tert-Butyl iodide 
• 507-19-7 t-butyl bromide 
• 92463-14-4 o-nitrophenyl phenylselenyl sulfide 
• 22082-57-1 t-butyl phenylazo sulfone 

Downstream Products

• 73501-53-8 1-(phenylseleno)-2-hydroxycyclohexane 
• 76570-77-9 1-(phenylseleno)-2-acetamidocyclohexane 
• 594-82-1 tetramethyl-2,2,3,3 butane 
• 75-28-5 Isobutane 
• 34172-60-6 bis(1,1-dimethylethyl) selenide 
• 115-11-7 isobutene 
• 3835-64-1 2,2-dimethyl-1-phenylpropan-1-ol 
• 1666-13-3 diphenyl diselenide 
• 1132-39-4 diphenylselenide 

Relevant articles and documents

O-(tert-butyl) Se-phenyl selenocarbonate: A convenient, bench-stable and metal-free precursor of benzeneselenol

A study by our laboratory shows that air, light and moisture stable O-(tert-butyl) Se-phenyl selenocarbonate could be employed as a safer, practical and efficient alternative to generate “in situ” benzeneselenol or benzeneselenolate anion under different and transition metal-free conditions. This procedure seems to be of general application since the nucleophilic selenium species obtained can be trapped by electrophiles such as alkyl halides, epoxides and electron-deficient alkenes and alkynes under different reaction conditions.

A mild and efficient method for preparing alkyl phenyl selenides from alkyl diphenyl phosphinites

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On the reactivity of indium(III) benzenechalcogenolates (chalcogen = sulfur and selenium) towards organyl halides for the synthesis of organyl phenyl chalcogenides

The reactivity of indium(III) benzenechalcogenolates (chalcogen = sulfur, selenium) towards organyl halides (organyl = alkyl, allyl, benzyl, acyl) was examined. A practical one-pot method to prepare organyl phenyl chalcogenides indium metal and diphenyl dichalcogenide was found. The coupling is fairly broad in scope and generally works better organyl halides capable to produce stable carbocations.