22326-34-7Relevant articles and documents
Formation of functionalized 2H-azirines through phio-mediated trifluoroethoxylation and azirination of enamines
Sun, Xiaoqian,Lyu, Youran,Zhang-Negrerie, Daisy,Du, Yunfei,Zhao, Kang
supporting information, p. 6222 - 6225 (2014/01/17)
A variety of enaminones and enamine carboxylic esters were converted to trifluoroethoxylated 2H-azirines through reactions with PhIO in trifluoroethanol (TFE). The cascade reaction is postulated to proceed via a PhIO-mediated oxidative trifluoroethoxylation and a subsequent azirination of the α-trifluoroethoxylated enamine intermediates.
Method for transferring amino acid into ketone acid(ester)
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Page/Page column 2, (2008/06/13)
A method for transferring amino acid into ketone acid (ester) may obtain ketone acid (ester) at low cost. The method uses sodium hypochlorous acid as oxidizing agent and proceeds oxidation reaction with amino acid or its derivatives so as to obtain ketone acid and its derivatives. The sodium hypochlorous acid is easily to get with low cost and the conditions of the reaction are mild so that the method meets the needs of the industry.
Ethyl 2,4-dioxoalkanoates as starting materials for a convenient route to 3(2H)furanones and 3(2H)furanimines
Baraldi,Barco,Benetti,et al.
, p. 235 - 242 (2007/10/02)
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