22391-05-5

Upstream product

• 104-88-1 4-chlorobenzaldehyde 
• 60-24-2 2-hydroxyethanethiol 

Downstream Products

• 104-88-1 4-chlorobenzaldehyde 
• 1822-73-7 phenylthioethylene 
• 121125-56-2 (2R,3R)-2-(4-Chloro-phenyl)-[1,3]oxathiolane 3-oxide 
• 121125-56-2 (2R,3S)-2-(4-Chloro-phenyl)-[1,3]oxathiolane 3-oxide 
• 2403-54-5 2-(4-chlorophenyl)-1,3-dioxolane 
• 6413-52-1 2-(4-chloro-phenyl)-[1,3]dioxane 
• 873-76-7 para-Chlorobenzyl alcohol 
• 74-11-3 para-chlorobenzoic acid 
• 1186296-21-8 dibenzyl (2R)-2-(4-chlorophenyl)-1,4-oxathiane-3,3-dicarboxylate 
• 1186296-19-4 dimethyl (2R)-2-(4-chlorophenyl)-1,4-oxathiane-3,3-dicarboxylate 
• 1186296-20-7 diethyl (2R)-2-(4-chlorophenyl)-1,4-oxathiane-3,3-dicarboxylate 
• 23229-32-5 2-(4-chlorophenyl)-1,3-dithiolane 

Relevant academic research and scientific papers

Visible light photoredox catalyzed deprotection of 1,3-oxathiolanes

An efficient visible light photoredox catalyzed aerobic deprotection of 1,3-oxathiolanes using organic dye Eosin Y as a photocatalyst is disclosed. The deprotection procedure features the use of a metal-free catalyst, mild conditions, a broad range of substrate scope, and good functional group tolerance. 35 examples were tested under the standard conditions and most of them afforded the deprotected products in modest to high yields.

Facile protection of carbonyl compounds as oxathiolanes and thioacetals promoted by PEG1000-based dicationic acidic ionic liquid as chemoselective and recyclable catalyst

Efficient oxathioacetalization and thioacetalization of carbonyl compounds have been achieved in high yields employing PEG1000-based dicationic acidic ionic liquid as a catalyst. The PEG ionic liquid and toluene have the advantages of both homo

Nickel(II) chloride hexahydrate catalyzed reaction of aromatic aldehydes with 2-mercaptoethanol: Formation of supramolecular helical assemblage of the product

Various aromatic aldehydes on reaction with 2-mercaptoethanol provided an unanticipated product, bis(2-hydroxyethyl)dithioacetals (3) as the major product along with the expected product 1,3-oxathiolanes (4) in the presence of 0.05 equiv amount of nickel(

An efficient method for the oxathioacetalization of carbonyl compounds using N-bromosaccharin as a catalyst

A mild and highly chemoselective method for the preparation of oxathiolane from aliphatic and aromatic aldehydes and ketones with 2-mercaptoethanol in the presence of catalytic amount of N-bromosaccharin at room temperature is reported.

Efficient procedure for oxathioacetalization using the novel ionic liquid

The novel ionic liquid with multi-SO3H groups has been synthesized through the simple procedure and its catalytic activity for the oxathioacetalization was investigated carefully at room temperature under solvent-free condition. The results sho

An efficient and mild deprotection of 1,3-oxathiolanes to carbonyl compounds using the superoxide ion

An efficient deprotection of 1,3-oxathiolanes to carbonyl compounds has been achieved under the mild reaction conditions of tetraethylammonium superoxide in an aprotic medium at room temperature.

Facile protection of carbonyl compounds as oxathiolanes and transoxathioacetalization of oxyacetals promoted by iron(III) trifluoroacetate or trifluoromethanesulfonate as chemoselective and recyclable catalysts

Oxathioacetalization of carbonyl compounds and transoxathioacetalization of O,O-acetals/ketals are reported under nearly neutral conditions promoted by iron(III) trifluoroacetate [Fe(CF3CO2)3] or trifluoromethanesulfonate

An efficient and chemoselective method for conversion of carbonyl compounds to 1,3-oxathiolanes with 2-mercaptoethanol catalyzed by TiCl 4-montmorillonite

Formation of 1,3-oxathiolanes from aldehydes and ketones using 2-mercaptoethanol in the presence of TiCl4-montmorillonite under mild reaction conditions in excellent yields is described. Chemoselective monothioacetalization of aldehyde in the p

Silica-supported perchloric acid (HClO4-SiO2): A versatile catalyst for tetrahydropyranylation, oxathioacetalization and thioacetalization

A simple and convenient synthetic protocol for the protection of hydroxyl group as tetrahydropyranyl ether as well as carbonyl functionality as oxathioacetal and thioacetal has been achieved using a catalytic amount of silica-supported perchloric acid und