23229-32-5

Basic information

• Product Name: 4-Chlorobenzaldehyde ethane-1,2-diyl dithioacetal
• Synonyms: 2-(4-Chlorophenyl)-1,3-dithiolane;4-Chlorobenzaldehyde (ethane-1,2-diyl)dithioacetal;4-Chlorobenzaldehyde ethane-1,2-diyl dithioacetal
• CAS NO: 23229-32-5
• Molecular Formula: C₉H₉ClS₂
• Molecular Weight: 216.7508
• Mol File: 23229-32-5.mol
• Article Data: 64

Chemical Properties

• Boiling Point: 336.8°Cat760mmHg
• Flash Point: 149.1°C
• Appearance: /
• Density: 1.323g/cm³
• Vapor Pressure: 0.000214mmHg at 25°C
• Refractive Index: 1.646
• CAS DataBase Reference: 4-Chlorobenzaldehyde ethane-1,2-diyl dithioacetal(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Chlorobenzaldehyde ethane-1,2-diyl dithioacetal(23229-32-5)
• EPA Substance Registry System: 4-Chlorobenzaldehyde ethane-1,2-diyl dithioacetal(23229-32-5)

Safety Data

• Hazardous Substances Data: 23229-32-5(Hazardous Substances Data)

Usage

InChI:InChI=1/C9H9ClS2/c10-8-3-1-7(2-4-8)9-11-5-6-12-9/h1-4,9H,5-6H2

Upstream product

• 540-63-6 ethane-1,2-dithiol 
• 74-11-3 para-chlorobenzoic acid 
• 22391-05-5 2-(4-chlorophenyl)-1,3-oxathiolane 
• 13086-93-6 (acetyloxy)(4-chlorophenyl)methyl acetate 
• 2403-54-5 2-(4-chlorophenyl)-1,3-dioxolane 
• 35583-10-9 3,9-di(p-chlorophenyl)-2,4,8,10-tetraoxaspiro[5.5]undecane 
• 138616-25-8 (E)-p-chlorobenzaldehyde N,N-dimethylhydrazone 
• 104-88-1 4-chlorobenzaldehyde 
• 65225-59-4 2-ethoxy-[1,3]dithiolane 

Downstream Products

• 104-88-1 4-chlorobenzaldehyde 
• 1476042-35-9 3-(2-(4-chlorophenyl)-1,3-dithiolan-2-yl)-1H-indole 
• 1476042-28-0 2-(2-(4-chlorophenyl)-1,3-dithiolan-2-yl)-1-p-tolylethanone 
• 1476042-27-9 1-(4-chlorophenyl)-2-(2-(4-chlorophenyl)-1,3-dithiolan-2-yl)ethanone 
• 1476042-26-8 1-(4-bromophenyl)-2-(2-(4-chlorophenyl)-1,3-dithiolan-2-yl)ethanone 
• 1476042-29-1 2-(2-(4-chlorophenyl)-1,3-dithiolan-2-yl)-1-(4-methoxy phenyl)ethanone 
• 1476042-25-7 2-(2-(4-chlorophenyl)-1,3-dithiolan-2-yl)-1-phenylethanone 
• 7335-27-5 ethyl 4-chlorobenzoate 
• 106-43-4 para-chlorotoluene 
• 36456-50-5 2-(4-Chlorphenyl)-1,1,3,3-tetraoxido-1,3-dithiolan 
• 20849-33-6 phenyl p-chlorobenzenedithiocarboxylate 
• 1822-73-7 phenylthioethylene 
• 123751-93-9 1-((E)-Buta-1,3-dienyl)-4-cyclopropyl-benzene 
• 113509-28-7 trimethyl<2-<4-<(trimethylsilyl)methyl>phenyl>ethenyl>silane 

Relevant articles and documents

Direct synthesis of dithioketals from N,N-dialkylhydrazones

Direct dithioketalisation of N,N-dialkylhydrazones promoted by BF3·Et2O or p-TsOH and 1,2-ethanedithiol in dry medium affords the corresponding dithiolanes in nearly quantitative yields. A variety of hydrazones derived from several k

Mesoporous sBa-15 silica catalyst functionalized with phenylsulfonic acid groups (SbA-15-ph-So3h) as efficient nanocatalyst for chemoselective thioacetalization of carbonyl compounds

In this research a Nano acidic catalyst was prepared and its efficiency on thioacetalization of carbonyl compounds was examined. For this aim we used modified SBA-15 as support, which have been modified by phenolic and sulfonic acid. SBA-15 is a member of

Indium-Catalyzed Reductive Dithioacetalization of Carboxylic Acids with Dithiols: Scope, Limitations, and Application to Oxidative Desulfurization

In this study an InI3-TMDS (1,1,3,3-tetramethyldisiloxane) reducing system effectively catalyzed the reductive dithioacetalization of a variety of aromatic and aliphatic carboxylic acids with 1,2-ethanedithiol or 1,3-propanedithiol leading to the one-pot preparation of either 1,3-dithiolane derivatives or a 1,3-dithiane derivative. Also, the intact indium catalyst continuously catalyzed the subsequent oxidative desulfurization of an in situ formed 1,3-dithiolane derivative, which led to the preparation of the corresponding aldehydes.

Ethyl lactate mediated thioacetalization of aldehydes at ambient temperature

Dithioacetalization reactions of aldehydes with thiols/thiophenols have been successfully achieved at room temperature by employing the green, bio-based ethyl lactate as the reaction medium. By means of this sustainable approach, a class of dithioacetals has been acquired with high diversity and efficiency.