227030-66-2Relevant academic research and scientific papers
RuO4-mediated oxidation of N-benzylated tertiary amines. Four- And three-membered azacycloalkanes as substrates
Florea, Cristina A.,H?rtopeanu, Anca,Stavarache, Cristina,Petride, Horia
, p. 294 - 307 (2018)
Similarly to N-benzylpiperidine and -pyrrolidine, N-benzylazetidine underwent RuO4-catalyzed oxidation by attack at both types of N-methylene C-H bonds: Endocyclic and exocyclic (benzylic). If the reaction is performed in the presence of cyanide, α-aminon
Strained azetidinium ylides: New reagents for cyclopropanation
Couty, Francois,David, Olivier,Larmanjat, Benedicte,Marrot, Jerome
, p. 1058 - 1061 (2008/02/05)
(Chemical Equation Presented) Azetidinium ylides showed a remarkable ability to perform the cyclopropanation of Michael acceptors. Ephedrine-derived azetidinium ylides allowed the formation of substituted cyclopropanes in good yields and at a high level o
