22710-73-2

Basic information

• Product Name: 1,2-diazido-1-phenylethane
• Synonyms: 1,2-diazido-1-phenylethane
• CAS NO: 22710-73-2
• Molecular Weight: 188.192
• Mol File: 22710-73-2.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1,2-diazido-1-phenylethane(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-diazido-1-phenylethane(22710-73-2)
• EPA Substance Registry System: 1,2-diazido-1-phenylethane(22710-73-2)

Safety Data

• Hazardous Substances Data: 22710-73-2(Hazardous Substances Data)

Upstream product

• 100-42-5 styrene 
• 4648-54-8 trimethylsilylazide 
• 160732-56-9 1-azido-1λ³-benzo[d][1,2]iodaoxol-3(1H)-one 

Downstream Products

• 96788-10-2 1-azido-1-phenyl-2-aminoethane 
• 138373-91-8 1-azido-1-phenyl-2-(N-tert-butoxycarbonylamino)ethane 
• 138457-47-3 1-azido-2-phenyl-2-(N-tert-butoxycarbonylamino)ethane 
• 95006-06-7 N,N'-(phenyl-ethanediyl)-bis-benzamide 
• 5700-56-1 1,2-diaminophenylethane 
• 129687-45-2 1-phenylethane-1,2-diaminium ditosylate 

Relevant articles and documents

Iodoazidation of Alkenes by Using Iodine Pentafluoride-Pyridine-Hydrogen Fluoride and Trimethylsilyl Azide

Iodoazidation of alkenes was carried out by using iodine pentafluoride-pyridine-hydrogen fluoride and trimethylsilyl azide. In the reactions of terminal alkenes, anti-Markovnikov products were formed selectively. Cyclohexene gave a mixture of cis- and trans-adducts. These results suggest the involvement of radical species in the reaction.

Palladium-Catalyzed Intermolecular Oxidative Diazidation of Alkenes

A palladium-catalyzed oxidative vicinal diazidation of alkenes has been developed, in which TMSN3 was used as azide source. Both styrenes and unactivated alkenes are suitable for this reaction. And trans-alkyldiazides were obtained as major products from cyclic alkenes with moderate to good diastereoselectivities. This reaction afforded an efficient way for the synthesis of useful 1,2-diamines after hydrogenation.

Copper-Catalyzed Vicinal Oxyazidation and Diazidation of Styrenes under Mild Conditions: Access to Alkyl Azides

A novel and efficient copper-catalyzed oxyazidation and diazidation of styrenes is described. The stable azidoiodine(III) reagent is used as an efficient azide radical source in this reaction. A variety of synthetically useful functional groups are compat