95006-06-7Relevant academic research and scientific papers
Iodine(III)-promoted intermolecular diamination of alkenes
Souto, Jose A.,Gonzalez, Yolanda,Iglesias, Alvaro,Zian, Debora,Lishchynskyi, Anton,Muniz, Kilian
supporting information; experimental part, p. 1103 - 1111 (2012/07/17)
A rapid and productive vicinal diamination of alkenes takes place in the presence of a hypervalent iodine(III) reagent and bissulfonimides as nitrogen sources. A total of more than 60 examples are presented. The reaction is characterized by its robustness and its wide substrate scope: it proceeds selectively with both terminal and internal alkenes and tolerates a range of functional groups.
An Expedient Synthesis of Vicinal Diamines from Alkenes and Cycloalkenes
Osowska-Pacewicka, Krystyna,Zwierzak, Andrzej
, p. 505 - 508 (2007/10/02)
A new procedure for the facile preparation of various vicinal diamines is developed that utilizes diethyl N-(β-bromoalkyl)phosphoramidates 2 easily accessible by ionic addition of diethyl N,N-dibromophosphoramidate (DBPA) to alkenes and cycloalkenes 1.Cru
