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227940-70-7

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227940-70-7 Usage

General Description

7-BENZYL-3-BOC-3,7-DIAZABICYCLO[3.3.1]NONAN-9-ONE is a chemical compound with the molecular formula C21H27NO3. It is a bicyclic compound that contains a diazabicyclo[3.3.1]nonane ring system with a benzyl group attached at the 7th position and a BOC (tert-butyloxycarbonyl) protective group at the 3rd position. 7-BENZYL-3-BOC-3,7-DIAZABICYCLO[3.3.1]NONAN-9-ONE has potential applications in organic synthesis and pharmaceutical research, as it can serve as a building block for the synthesis of complex organic molecules. Its unique structure makes it a valuable tool for the development of new drugs and the study of chemical reactions.

Check Digit Verification of cas no

The CAS Registry Mumber 227940-70-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 2,2,7,9,4 and 0 respectively; the second part has 2 digits, 7 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 227940-70:
(8*2)+(7*2)+(6*7)+(5*9)+(4*4)+(3*0)+(2*7)+(1*0)=147
147 % 10 = 7
So 227940-70-7 is a valid CAS Registry Number.

227940-70-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name tert-butyl 7-benzyl-9-oxo-3,7-diazabicyclo[3.3.1]nonane-3-carboxylate

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:227940-70-7 SDS

227940-70-7Relevant articles and documents

Modular synthesis of functionalized bis-bispidine tetraazamacrocycles

Wang, Zhuo,Miller, Erin J.,Scalia, Samantha J.

, p. 6540 - 6543 (2011)

An effective synthesis is reported for the construction of highly rigid and preorganized bis-bispidine tetraazamacrocycles bearing either identical or different functionalities. Using essential building blocks derived from N-Boc-N'-allylbispidinone, the modular approach facilitates independent incorporation of the functional groups to the macrocyclic framework as well as selective derivatization of one functionality in the presence of another.

A tryptophan-containing fluorescent intramolecular complex as a designer peptidic proton sensor

Haridas,Yadav, Anita,Sharma, Sakshi,Pandey, Siddharth

, p. 15046 - 15053 (2016)

Pyrene and tryptophan groups judiciously placed on a novel molecular scaffold, namely, bispidine exhibited fluorescence due to the formation of an unprecedented emissive intramolecular complex in polar solvents. Upon protonation, the emission signal from the pyrene unit enhances at the expense of the emission signal from the complex. The probe demonstrates good sensitivity, excellent selectivity, and adequate reversibility towards proton sensing. The present design based on the bispidine scaffold opens up newer opportunities for the design of novel bispidine-peptide sensors.

Unsymmetrical pincer CNN palladium complex of 7-ferrocenylmethyl-3-methyl-3,7-diazabicyclo[3.3.1]nonane

Bulygina, Ludmila A.,Kagramanov, Nikolay D.,Khrushcheva, Natalya S.,Lyssenko, Konstantin A.,Peregudov, Aleksander S.,Sokolov, Viacheslav I.

, p. 169 - 175 (2017/06/20)

The new unsymmetrical ferrocenyl containing bispidine derivative 7 was synthesized as a ligand precursor in five steps starting from N-Boc-4-oxopiperidine. The corresponding palladium CNN pincer complex 8 was prepared by direct cyclopalladation of the ligand 7 with Li2PdCl4 in MeOH. The molecular structure of the obtained palladacycle was determined by multinuclear NMR (1H, 13C, 15N) and confirmed by X-ray diffraction analysis. The pincer complex 8 demonstrated high catalytic activity in some cross-coupling reactions of aryl halides with phenylboronic acid, norbornene and ethyl acrylate.

Cyclopalladate complex of 3-benzyl-7-methyl-3,7-diazabicyclo[3.3.1]nonane

Bulygina,Khrushcheva,Peregudov,Sokolov

, p. 2479 - 2484 (2017/05/09)

A new (C,N,N)-pincer cyclopalladate unsymmetrical complex of 3-benzyl-7-methyl-3,7-diazabicyclo[3.3.1]nonane (3-benzyl-7-methylbispidine) was synthesized and characterized. Catalytic performance of this complex was examined in the Heck and Suzuki reactions and in the norbornene hydroarylation.

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