22926-97-2

Basic information

• Product Name: 2-(4-methoxyphenyl)-1-phenylpropan-2-ol
• Synonyms: 2-(4-methoxyphenyl)-1-phenylpropan-2-ol
• CAS NO: 22926-97-2
• Molecular Weight: 242.318
• Mol File: 22926-97-2.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: 2-(4-methoxyphenyl)-1-phenylpropan-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(4-methoxyphenyl)-1-phenylpropan-2-ol(22926-97-2)
• EPA Substance Registry System: 2-(4-methoxyphenyl)-1-phenylpropan-2-ol(22926-97-2)

Safety Data

• Hazardous Substances Data: 22926-97-2(Hazardous Substances Data)

Upstream product

• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 6921-34-2 benzylmagnesium chloride 
• 1712-69-2 1-isopropenyl-4-methoxybenzene 
• 100-63-0 phenylhydrazine 
• 100-52-7 benzaldehyde 
• 5281-18-5 benzaldehyde, hydrazone 
• 100-44-7 benzyl chloride 
• 100-39-0 benzyl bromide 

Downstream Products

• 5912-82-3 (E)-2-(4-methoxyphenyl)-1-phenylpropene 
• 1380439-41-7 (Z)-2-(4-methoxyphenyl)-1-phenylprop-1-ene 
• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 17742-17-5 β-4-methoxyphenyl-β-methylstyrene 
• 22927-03-3 1-methoxy-4-(3-phenylprop-1-en-2-yl)benzene 
• 782-92-3 1-(4-benzylphenyl)ethanone 

Relevant articles and documents

Iron-Catalyzed Nucleophilic Addition Reaction of Organic Carbanion Equivalents via Hydrazones

Earth-abundant and well-defined iron complexes are found to be cheap and effective catalysts for a series of "umpolung" nucleophilic additions of hydrazones. The new catalytic system not only maintains the broad substrate scope of an earlier expensive ruthenium system but also attains chemoselectivity of different kinds of carbonyl groups. Furthermore, the iron catalyst enables this reaction at ambient temperature.

Iodine-catalyzed transformation of aryl-substituted alcohols under solvent-free and highly concentrated reaction conditions

Iodine-catalyzed transformations of alcohols under solvent-free reaction conditions (SFRC) and under highly concentrated reaction conditions (HCRC) in the presence of various solvents were studied in order to gain insight into the behavior of the reaction intermediates under these conditions. Dimerization, dehydration and substitution were the three types of transformations observed with benzylic alcohols. Dimerization and substitution reactions were predominant in the case of primary- and secondary alcohols, whereas dehydration prevailed in the case of tertiary alcohols. The relative reactivity of substituted 1-phenylethanols in I2-catalyzed dimerization under SFRC provided a good Hammett plot ρ+ = -2.8 (r2 = 0.98), suggesting the presence of electron-deficient intermediates with a certain degree of developed charge in the rate-determining step.

Intramolecular 10,10a-[2+2] photocycloaddition reactions of phenanthrenes with linked styrene

Intramolecular photocycloaddition reactions of styrene linked 9-cyanophenanthrenes led to formation of C-9 C-10 [2+2] cycloadducts which underwent cycloreversion under the prolonged irradiation conditions to regenerate the starting substrates. Unusual 8-membered ring products were irreversibly formed in these processes. Product distributions were governed by substituent controlled, donor-acceptor interactions that direct generation of two intramolecular singlet exciplexes, which serve as intermediates in the pathways to formation of 9,10- and 10,10a-[2+2] adducts.