22956-11-2Relevant articles and documents
OPTICAL INDUCTION - IV Optical Induction by Using Homogeneous Catalyst
Ahuja, R. R.,Natu, A. A.,Gogte, V. N.
, p. 4743 - 4744 (1980)
Better optical induction during Michael addition has been achieved by using new homogeneous catalysts based on quinine and quinidine.
SmI2-mediated reductive cyclization of β-arylthio ketones: A facile and diastereoselective synthesis of thiochroman derivatives
Mao, Hui,You, Bing-Xin,Zhou, Lie-Jin,Xie, Ting-Ting,Wen, Yi-Hang,Lv, Xin,Wang, Xiao-Xia
, p. 6157 - 6166 (2017/08/02)
SmI2-mediated reductive cyclization of β-arylthio ketones to generate thiochroman derivatives is not a generally observed process and the reported examples are limited to geminal disubstitution in the substrates. The results of the current stud
Thioboration of α,β-unsaturated ketones and aldehydes toward the synthesis of β-sulfido carbonyl compounds
Civit, Marc G.,Sanz, Xavier,Vogels, Christopher M.,Webb, Jonathan D.,Geier, Stephen J.,Decken, Andreas,Bo, Carles,Westcott, Stephen A.,Fernández, Elena
supporting information, p. 2148 - 2154 (2015/05/19)
Herein a direct β-sulfido carbonyl compound synthesis by the easy activation of RS-Bpin reagents with α,β-unsaturated ketones and aldehydes is reported. This convenient methodology can be performed at room temperature with no other additives. The key poin