23062-75-1

Basic information

• Product Name: 5-methyl-2-phenyl-4,5-dihydro-1,3-thiazole
• Synonyms: 5-methyl-2-phenyl-4,5-dihydro-1,3-thiazole
• CAS NO: 23062-75-1
• Molecular Formula: C₁₀H₁₁NS
• Molecular Weight: 0
• Mol File: 23062-75-1.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 285.4°Cat760mmHg
• Flash Point: 126.4°C
• Appearance: /
• Density: 1.14g/cm³
• Vapor Pressure: 0.00482mmHg at 25°C
• Refractive Index: 1.617
• CAS DataBase Reference: 5-methyl-2-phenyl-4,5-dihydro-1,3-thiazole(CAS DataBase Reference)
• NIST Chemistry Reference: 5-methyl-2-phenyl-4,5-dihydro-1,3-thiazole(23062-75-1)
• EPA Substance Registry System: 5-methyl-2-phenyl-4,5-dihydro-1,3-thiazole(23062-75-1)

Safety Data

• Hazardous Substances Data: 23062-75-1(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H11NS/c1-8-7-11-10(12-8)9-5-3-2-4-6-9/h2-6,8H,7H2,1H3

Upstream product

• 10283-95-1 N-allylbenzamide 
• 93424-04-5 N-benzyl N-(propenyl-1) orthophenyl benzamide 
• 100-52-7 benzaldehyde 
• 23054-66-2 N-(2-hydroxypropyl)benzamide 
• 93424-16-9 N-benzyl N-propenyl-1 thiobenzamide 
• 92877-45-7 N-(2-Hydroxy-propyl)-thiobenzamide 
• 133523-82-7 2-phenyl-5-((phenylselanyl)methyl)-4,5-dihydrothiazole 
• 130012-62-3 N-prop-2-enylbenzocarbothioamide 
• 2403-33-0 2-bromopropylamine hydrobromide 
• 2227-79-4 benzenecarbothioamide 
• 860523-40-6 N-(2-bromo-propyl)-benzamide 

Downstream Products

• 86674-60-4 2-amino-1-methylethanesulfonic acid 
• 65-85-0 benzoic acid 

Relevant articles and documents

Divergent regioselectivity in photoredox-catalyzed hydrofunctionalization reactions of unsaturated amides and thioamides

A direct method to construct 2-oxazolines and 2-thiazolines from corresponding allylic amides and thioamides is reported. The redox-neutral intramolecular hydrofunctionalization is enabled by a dual catalyst system comprised of 9-mesityl-N-methyl acridini

Sulfur-containing heterocycles derived by reaction of N-thioacylamino alcohols with Lawesson's reagent and saponification of N-thioacylamino esters

The treatment of 2-N-thioacylamino alcohols (1) with Lawesson's reagent [LR: 2,4-bis(p-methoxyphenyl)-1,3,2,4-dithiaphosphetane 2,4-disulfide] afforded the sulfur-containing heterocycles, 1,3-thiazolines (2) in moderate to good yields, exclusively. The sa

Organoselenium- and Proton-Mediated Cyclization Reactions of Allylic Amides and Thioamides. Syntheses of 2-Oxazolines and 2-Thiazolines

A variety of allylic amides and thioamides were treated with phenylselenenyl bromide in chloroform to give, via 5-exo cyclization, 2-oxazolines and 2-thiazolines, respectively, carrying a (phenylselenenyl)methyl substituent in the 5-position.In some cases (N-crotyl- and N-cinnamylamides/thioamides), dihydro-1,3-oxazines/-thiazines were formed via 6-endo cyclization.The phenylselenenyl group of the cyclofunctionalization products was slowly eliminated by treatment with m-chloroperbenzoic acid to introduce unsaturation in the resulting oxazoline/thiazoline.Reductive removal of the phenylselenenyl group was effected by treatment with triphenyltin hydride.This reaction was sometimes accompanied by a rearrangement of the heterocyclic ring.Proton-induced cyclizations of allylic thioamides to give 2-thiazolines was slowly but efficiently effected in boiling toluene containing a catalytic amount of p-toluenesulfonic acid.