2314-49-0Relevant academic research and scientific papers
An efficient, one-pot synthesis of trithiocarbonates from alcoholic tosylates using the Cs2CO3/CS2 system
Chaturvedi, Devdutt,Mishra, Nisha,Chaturvedi, Amit K.,Mishra, Virendra
, p. 1467 - 1470 (2008)
A single-step novel protocol for the preparation of symmetrical trithiocarbonates from a corresponding variety of primary, secondary, and tertiary alcoholic tosylates using the Cs2CO3/CS 2 system, was developed. This protocol is mild and more efficient than the reported methods.
A facile KF/Al2O3-mediated, one-pot synthesis of symmetrical trithiocarbonates from alkyl halides and carbon disulfide
Movassagh, Barahman,Soleiman-Beigi, Mohammad,Nazari, Mohammad
, p. 22 - 23 (2008)
A facile, efficient, and convenient method has been developed for the one-pot synthesis of symmetrical trithiocarbonates from carbon disulfide and various alkyl halides in the presence of KF/Al2O3 in DMF at room temperature. Copyright
Mild and efficient one-step synthesis of trithiocarbonates using minimum amount of CS2
Aoyagi, Naoto,Ochiai, Bungo,Mori, Hideharu,Endo, Takeshi
, p. 636 - 638 (2006)
Symmetrical dialkyl trithiocarbonates were obtained from various alkyl halides with an equivalent of carbon disulfide and cesium carbonate in polar aprotic solvents, although the conventional synthesis of trithiocarbonates had required large excess amount of carbon disulfide. This reaction proceeds under ambient conditions, for example, at room temperature under an aerial atmosphere, without strong base nor phase-transfer catalyst. Georg Thieme Verlag Stuttgart.
A convenient one-pot method for the synthesis of symmetrical dialkyl trithiocarbonates using NH4OAc under mild neutral conditions
Arzehgar, Zeinab,Ahmadi, Hosna
, p. 303 - 306 (2018/11/01)
A facial, new, one-pot method for the preparation of symmetrical organic trithiocarbonates from various alkyl halides and carbon disulfide is described. This is a convenient, clean, and mild procedure, which involves the use of the neutral, nontoxic, commercially available, and inexpensive reagent NH4OAc in the preparation of the trithiocarbonate ion from carbon disulfide.
Investigations of the Thermal Responsiveness of 1,4,2-Oxathiazoles
Hewitt, Russell J.,Ong, Michelle Jui Hsien,Lim, Yi Wee,Burkett, Brendan A.
supporting information, p. 6687 - 6700 (2015/10/29)
The first systematic study of the thermal rearrangement/fragmentation of 5,5-disubstituted 1,4,2-oxathiazoles into isothiocyanates is reported. Structure-activity relationships reveal that the choice of substituent at the 5-position of the 1,4,2-oxathiazoles is the predominant factor to influence the ease of fragmentation.
Superbasic system CsOH/DMSO as a reagent for a fast one-step synthesis of symmetrical dialkyl trithiocarbonates
Yousefi, Ali
, p. 672 - 677 (2015/11/18)
Symmetrical dialkyl trithiocarbonates were readily synthesized in excellent yields by one-step reaction of carbon disulfide and various alkyl halides under mild reaction conditions in the presence of cesium hydroxide as a super basic system. This method provides a synthesis of symmetrical dialkyl trithiocarbonates in short reaction times without the use of highly toxic starting materials.
An efficient one-pot approach to the synthesis of symmetric trithiocarbonates from carbon disulfide and alkyl halides using imidazole
Soleiman-Beigi, Mohammad,Taherinia, Zahra
, p. 470 - 476 (2014/08/18)
A novel method is reported for the synthesis of symmetric dialkyl and cyclic (5, 6 and 7 member) trithiocarbonates from alkyl halides and carbon disulfide in the presence of imidazole and water in DMSO under mild reaction conditions. Imidazole is used as an inexpensive, non-toxic and readily available catalyst in this procedure.
K3PO4-mediated one-pot synthesis of symmetrical trithiocarbonates
Movassagh, Barahman,Alapour, Saba
, p. 222 - 226 (2013/08/26)
A new procedure has been developed for synthesis of symmetrical trithiocarbonates by one-pot reaction of carbon disulfide, and various alkyl halides in dimethylformamide using K3PO4 as an inexpensive and effective reagent.
TBAH-catalyzed one-pot synthesis of symmetrical trithiocarbonates from alkyl halides and carbon disulfide under neat aqueous conditions
Soleiman-Beigi, Mohammad,Arzehgar, Zeinab,Movassagh, Barahman
experimental part, p. 392 - 394 (2010/04/05)
A novel and efficient, tetra-n-butylammonium hydroxide catalyzed, one-pot protocol has been developed for the synthesis of symmetrical trithiocarbonates from alkyl halides and carbon disulfide under neat aqueous conditions. Georg Thieme Verlag Stuttgart - New York.
Triethylamine-catalyzed one-pot synthesis of trithiocarbonates from carbon disulfide, thiols, and alkyl halides in water
Movassagh, Barahman,Soleiman-Beigi, Mohammad
experimental part, p. 927 - 930 (2009/09/06)
Symmetrical and unsymmetrical trithiocarbonates were prepared by a simple and efficient one-pot reaction of thiols, carbon disulfide, and alkyl halides in the presence of triethylamine in water at room temperature.
