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2319-38-2

Triphenylsilyl hydroperoxide (TPSH) is a chemical compound with the formula (Ph3Si)OOH, where "Ph" represents a phenyl group. It is a stable, colorless, and crystalline solid that is widely used as a selective oxidizing agent in organic synthesis. TPSH is known for its ability to transfer an oxygen atom to various substrates, making it a valuable tool in the preparation of alcohols, epoxides, and other oxygen-containing compounds. Its stability and reactivity profile make it a preferred choice over traditional hydroperoxides, which can be hazardous and difficult to handle. The compound's structure, with a bulky triphenylsilyl group, contributes to its stability and selectivity in oxidation reactions.

2319-38-2

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2319-38-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 2319-38-2 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,3,1 and 9 respectively; the second part has 2 digits, 3 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 2319-38:
(6*2)+(5*3)+(4*1)+(3*9)+(2*3)+(1*8)=72
72 % 10 = 2
So 2319-38-2 is a valid CAS Registry Number.

2319-38-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name hydroperoxy(triphenyl)silane

1.2 Other means of identification

Product number -
Other names triphenylsilyl hydroperoxide

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:2319-38-2 SDS

2319-38-2Relevant articles and documents

Hydroperoxo double hydrogen bonding: Stabilization of hydroperoxo complexes exemplified by triphenylsilicon and triphenylgermanium hydroperoxides

Churakov, Andrei V.,Grishanov, Dmitry A.,Lev, Ovadia,Medvedev, Alexander G.,Mikhaylov, Alexey A.,Prikhodchenko, Petr V.

, p. 1922 - 1928 (2020/03/23)

Triphenyl silicon hydroperoxide and its isostructural germanium complex were characterized by single crystal X-ray analysis revealing H-bonding of two triphenylhydroperoxocomplexes, with each hydroperoxo ligand acting as a hydrogen donor and a hydrogen ac

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