2338-64-9

Usage

Uses

1,1,2,2,3,3-Hexafluoroindene is used as an electrolyte for secondary battery.

Upstream product

• 116-14-3 polytetrafluoroethylene 
• 108-95-2 phenol 
• 367-12-4 2-fluorophenol 
• 95-57-8 2-monochlorophenol 
• 95-56-7 2-hydroxybromobenzene 
• 100-66-3 methoxybenzene 
• 615-42-9 1,2-Diiodobenzene 
• 1492127-10-2 [(acetonitrile)₂Zn((CF₂)₃)₂Zn(acetonitrile)₂] 
• 938-24-9 indantrione 
• 106-48-9 4-chloro-phenol 
• 371-41-5 4-Fluorophenol 

Relevant academic research and scientific papers

Mild, safe, and versatile reagents for (CF2)n transfer and the construction of fluoroalkyl-containing rings

The preparation of new dizinc reagents [(MeCN)2Zn((CF 2)n)2Zn(MeCN)2] (n = 3, 4, and 6) is reported. We show that the C4 reagent can readily transmetalate nickel to form a mononuclear perfluoronickelacycle. We also demonstrate that the reagents can be used to prepare novel fluoroorganics containing either perfluoroalkyl ring systems or perfluoroalkyl linked arenes under relatively mild conditions.

THERMOLYTIC TRANSFORMATION OF POLYFLUORINATED ORGANIC COMPOUNDS. XXVIII. PRODUCTION OF POLYFLUOROINDANES AND SOME OF THEIR CHARACTERISTICS

The copyrolysis (620 deg C) of phenol and ortho- and para-halogenophenols with perfluoroethylene in a flow-type system was investigated. 1,1,2,2,3,3-hexafluoroindane was mostly obtained from phenol, anisole, and o-bromophenol; o-chlorophenol gives the same compounds as the main product together with 1,1,2,2,3,3-hexafluoro-4-chloroindane; in the case of o-fluorophenol the main reaction products are 1,1,2,2,3,3-hexafluoroindane and 1,1,2,2,3,3,4- and 1,1,2,2,3,3,5-heptafluoroindanes.With perfluoroethylene para-halogenophenols form 1,1,2,2,3,3-hexafluoro-5-halogenoindanes.The paths to the formation of the polyfluoroindanes are discussed.When heated with nitric acid, 1,1,2,2,3,3-hexafluoroindane gives mainly 4-nitro-1,1,2,2,3,3-hexafluoroindane, from which the corresponding amino derivative is obtained by reduction.