235101-20-9

Upstream product

• 1779-49-3 Methyltriphenylphosphonium bromide 
• 235101-19-6 (R)-(+)-3-(methoxymethoxy)-2-(4-methoxyphenyl)-2-methylpropanal 
• 790260-90-1 (R)-(+)-2-(methoxycarbonyl)-2-(4-methoxyphenyl)propionic acid 
• 235101-18-5 methyl (R)-(+)-3-(methoxymethoxy)-2-(4-methoxyphenyl)-2-methylpropionate 
• 959903-74-3 methyl (R)-(+)-3-hydroxy-2-(4-methoxyphenyl)-2-methylpropionate 
• 235101-25-4 (R)-(+)-3-(methoxymethoxy)-2-(4-methoxyphenyl)-2-methylpropanol 

Downstream Products

• 235101-21-0 (R)-2-(4-methoxyphenyl)-2-methylbut-3-en-1-ol 
• 87580-60-7 (E)-3-(4-methoxyphenyl)but-2-enal 
• 191212-52-9 (R)-(-)-4-(4-methoxyphenyl)-4-methylhex-5-en-1-al 
• 191212-50-7 (R)-1-(3,7-dimethylocta-1,6-dien-3-yl)-4-methoxybenzene 
• 235101-22-1 (R)-2-(4-Methoxy-phenyl)-2-methyl-but-3-enal 
• 235101-23-2 methyl (R)-(-)-4-(4-methoxyphenyl)-4-methylhex-5-enoate 
• 235101-15-2 ethyl trans-(S)-(+)-4-(4-methoxyphenyl)-4-methylhexa-2,5-dienoate 

Relevant academic research and scientific papers

Total synthesis of (-)-sporochnol A, the fish deterrent, from a chiral malonate

From a single chiron, the homochiral benzylic malonic acid ester (R)- (+)-2 available with high enantiomeric excess by enzymatic hydrolysis (PLE acetonic powder), enantiomerically pure (-)-sporochnol A 1 was prepared. This versatile method allows preparation of sporochnol 1, via aldehydes 7 and 15, in good overall yield.