2397-29-7

Upstream product

• 88070-48-8 N-methylbenzamide 
• 62-53-3 aniline 
• 3409-96-9 benzenesulfonyl-benzoyl-methyl-amine 
• 29019-38-3 N,N'-dimethylbenzoamidine 
• 103-72-0 phenyl isothiocyanate 
• 586-96-9 Nitrosobenzene 
• 21737-87-1 N-methyl benzimidoyl chloride 
• 4903-36-0 N-phenyl-benzimidoyl chloride 
• 74-89-5 methylamine 
• 93-98-1 N-phenyl benzoyl amide 
• 98-88-4 benzoyl chloride 
• 13712-75-9 3-methyl-2,4-diphenyloxazolium-5-olate 
• 15994-92-0 N-Methyl-N'-phenyl-N-benzoyl-benzamidin 

Downstream Products

• 61656-93-7 C₁₈H₁₉N₃O₃ 
• 40421-93-0 N-Methyl-N'-phenyl-N-(phenylcarbamoyl)-benzamidin 
• 2556-46-9 N,N'-diphenylbenzamidine 
• 61505-50-8 C₂₂H₁₈N₂O 
• 89536-05-0 C₁₅H₁₃N₃O₃S 
• 76677-96-8 7,8,9,10-Tetrachlor-2,5-imino-3-methyl-2,5,11-triphenyl-2,3,4,5-tetrahydro-1,6,3-benzodioxazocin-4-on 
• 34028-17-6 N-methylbenzamidine 

Relevant academic research and scientific papers

Transition Metal-Free Visible Light-Driven Photoredox Oxidative Annulation of Arylamidines

A fast catalytic synthesis of multisubstituted quinazolines from readily available amidines via visible light-mediated oxidative C(sp3)-C(sp2) bond formation has been established. This reaction is a metal-free oxidative coupling catalyzed by a photoredox organocatalyst. The protocol features low catalyst loading (1 mol %).

Synthesis of Amides and Amidines by Reaction of Carboxylic Acids and Amines in the Presence of Polyphophoric Acid Trimethylsilyl Ester (PPSSE)

The reaction between amines and carboxylic acids in the presence of poliphosphoric acid trimethylsilylester (PPSE) has been investigated from the view point of the synthesis of amides and amidines.Benzanilide was selectively prepared from benzoic acid and aniline in the presence of PPSE and pyridine at 100 degC, whereas a mixture of benzanilide and N,N'-diphenylbenzamidine was obtained without the use of pyridine.The reaction at 160 degC almost exclusively gave N,N'-diphenylbenzamidine.Various simmetrical amidines were obtained from combinations of carboxylic acids and aromatic amines in high yields by simply heating at 160 degC with four molar amounts of PPSE.The reactions of aliphatic and aromatic amines with N-monosubstituted and N,N-disubstituted amides also afforded corresponding unsymmetrical amidines under the same conditions.The reaction mechanism is discussed in some detail.