23973-51-5

Basic information

• Product Name: Allylthioacetate
• Synonyms: Allylthioacetate;S-Prop-2-enyl ethanethioate
• CAS NO: 23973-51-5
• Molecular Formula: C₅H₈OS
• Molecular Weight: 115.17348
• Product Categories: thioester Flavor
• Mol File: 23973-51-5.mol
• Article Data: 14

Chemical Properties

• Boiling Point: 132 °C at 760 mmHg
• Flash Point: 30.5 °C
• Appearance: /
• Density: 0.99 g/cm³
• CAS DataBase Reference: Allylthioacetate(CAS DataBase Reference)
• NIST Chemistry Reference: Allylthioacetate(23973-51-5)
• EPA Substance Registry System: Allylthioacetate(23973-51-5)

Safety Data

• Hazardous Substances Data: 23973-51-5(Hazardous Substances Data)

Usage

General Description

Allylthioacetate is a chemical compound represented by the formula C5H8OS. It falls under the category of organosulfur compounds, specifically being an allyl compound, meaning that it has the capability to form a carbon-carbon double bond. This chemical has industrial applications and can be synthesized in the laboratory. Characteristic features of this compound include its strong, pungent smell and its potentially hazardous nature. Appropriate safety measures need to be taken when handling Allylthioacetate, including the use of gloves and eye protection, as well as ensuring good ventilation in the working area.

Upstream product

• 34832-35-4 sodium thioacetate 
• 107-05-1 3-chloroprop-1-ene 
• 106-95-6 allyl bromide 
• 6728-21-8 allyl mesylate 
• 507-09-5 tiolacetic acid 
• 10387-40-3 potassium thioacetate 
• 870-23-5 prop-2-ene-1-thiol 
• 108-24-7 acetic anhydride 
• 16621-54-8 thioacetic acid S-(2,3-dichloro-propyl ester) 
• 107-18-6 allyl alcohol 

Downstream Products

• 870-23-5 prop-2-ene-1-thiol 
• 1448510-33-5 S-(1,7-dioxo-1,7-diphenylheptan)-4-yl O-ethyl carbonodithioate 
• 2179-57-9 diallyl disulphide 
• 14418-84-9 allylsulfonyl chloride 

Relevant articles and documents

Synthesis and preliminary evaluation of the anti-cancer activity on A549 lung cancer cells of a series of unsaturated disulfides

We synthesized a series of small symmetrical unsaturated disulfides by a multi-step reaction starting from organic alcohols, and we performed a preliminary test to evaluate the effect of these compounds on the viability of A549 lung cancer cells. The garlic-derived natural compound diallyl disulfide, known for its anticancer activity, was used as the lead compound in this study. We synthesized five DADS analogues having different carbon chain lengths and different positions of the double bonds. Two analogues exhibited a promising antitumor activity in vitro, and the allylic double bond did not seem to be the main driving force.

Method of manufacturing compds. Allylnaphthol

PROBLEM TO BE SOLVED: To provide a production method of an allyl compound of carrying out the dehydration allylation of a substrate having S, C or N which is a nucleophilic atom, especially S under the presence of a catalyst system consisting of a catalyst precursor having a specific structure and a specific ligand. SOLUTION: The production method of allyl compounds comprises as follow. A catalyst precursor chosen from Formula (1) and Formula (2) and a ligand are mixed, or a catalyst precursor, an allyl alcohol, and a ligand are mixed, then allyl alcohols and a substrate are blended and made to react. The ligand is quinaldic acid or picolinic acid, and the substrate is thiols, thiocarboxylic acids or the like. [Ru(C5H5)(CH3CN)3]PF6(1). [Ru[C5(CH3)5](CH3CN)3]PF6(2). COPYRIGHT: (C)2012,JPOandINPIT

OLEFIN METATHESIS REACTIONS OF AMINO ACIDS, PEPTIDES AND PROTEINS CONTAINING ALLYL SULFIDE GROUPS

A method for the modification of an amino acid, protein or peptide is disclosed. The method comprises reacting a carbon-carbon double bond-containing compound with an amino acid, a protein or a peptide containing an allyl sulfide group in the presence of a catalyst which promotes olefin metathesis, to form a modified amino acid, protein or peptide. Preferred carbon-carbon double bond-containing compounds include carbohydrates.