24299-77-2Relevant articles and documents
Synthesis, structure and reactivity of a macrocyclic imine: Aza-[13]-macrodiolides
Ma, Jun,Vannam, Raghu,Terwilliger, Daniel W.,Peczuh, Mark W.
supporting information, p. 4255 - 4259 (2014/07/22)
The in situ synthesis and subsequent reactions of macrocylic imine 2 are reported. The imine was trapped with cyanotrimethylsilane to give α-amino nitrile aza-[13]-macrodiolides in a 1:1 ratio of diastereomers. A crystal structure of the syn α-cyano nitrile diastereomer, 7a, provided insights into the lack of selectivity in reactions of 2 relative to macrocyclic alkene 1. Reactions to functionalize the syn diastereomer 7a are also reported.
PHOTOCYCLISATION OF KETO-LACTAMS. A NEW SYNTHESIS OF FUNCTIONALIZED 1-AZA-BICYCLO(X.Y.0.)ALKANES
Azzouzi, Assia,Dufour, Monique,Gramain, Jean-Claude,Remuson, Roland
, p. 133 - 148 (2007/10/02)
A series of 1-azabicyclo(x.y.0)alkanes has been synthesized using an intramolecular photoreduction.The methodology consists of a regioselective abstraction of a hydrogen α to the nitrogen of an amide by the triplet T1(n, ?*) of a carbonyl derivative.
Synthesis in the diazasteroid group. XV. Syntheses of the 5,9- and 8,13-diazasteroids
Takahata,Okajima,Yamazaki
, p. 3632 - 3638 (2007/10/02)
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