24393-51-9

Basic information

• Product Name: 2-Propenoic acid, 3-(2-chlorophenyl)-, ethyl ester, (2E)-
• CAS NO: 24393-51-9
• Molecular Formula: C11H11ClO2
• Molecular Weight: 210.66
• Mol File: 24393-51-9.mol
• Article Data: 50

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 3-(2-chlorophenyl)-, ethyl ester, (2E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 3-(2-chlorophenyl)-, ethyl ester, (2E)-(24393-51-9)
• EPA Substance Registry System: 2-Propenoic acid, 3-(2-chlorophenyl)-, ethyl ester, (2E)-(24393-51-9)

Safety Data

• Hazardous Substances Data: 24393-51-9(Hazardous Substances Data)

Upstream product

• 64-17-5 ethanol 
• 704-96-1 trans-2-chlorocinnamic acid 
• 108-90-7 chlorobenzene 
• 140-88-5 ethyl acrylate 
• 65946-56-7 1-ethoxy-1-(trimethylsiloxy)-2-(trimethylsilyl)ethene 
• 89-98-5 2-chloro-benzaldehyde 
• 1099-45-2 ethyl (triphenylphosphoranylidene)acetate 
• 89-97-4 2-CHLOROBENZYLAMINE 
• 120681-06-3 3-(2-chlorophenyl)propenoyl chloride 
• 3752-25-8 o-chlorocinnamic acid 
• 95-50-1 1,2-dichloro-benzene 
• 867-13-0 diethoxyphosphoryl-acetic acid ethyl ester 
• 141-82-2 malonic acid 
• 694-80-4 2-bromo-1-chlorobenzene 

Downstream Products

• 1255778-46-1 1,4-diethyl 2-(2-chlorophenyl)butanedioate 
• 1333193-66-0 triethyl 2-(2-chlorophenyl)-1,1,2-ethanetricarboxylate 
• 55579-68-5 5-(2-chlorophenyl)-1,3-cyclohexanedione 
• 1361194-53-7 4-(2-chlorophenyl)quinolin-2(1H)-one 
• 29655-71-8 ethyl 3-(2-chlorophenyl)-4-nitrobutanoate 
• 1794-45-2 2-chlorocinnamaldehyde 
• 960355-42-4 ethyl 5-(2-chloro-phenyl)-penta-2,4-dienoate 
• 15542-32-2 (2E,4E)-5-(2-chlorophenyl)penta-2,4-dienoic acid 

Relevant articles and documents

Photoinduced Regioselective Olefination of Arenes at Proximal and Distal Sites

The Fujiwara-Moritani reaction has had a profound contribution in the emergence of contemporary C-H activation protocols. Despite the applicability of the traditional approach in different fields, the associated reactivity and regioselectivity issues had

Enantiodivergent One-Pot Synthesis of Axially Chiral Biaryls Using Organocatalyst-Mediated Enantioselective Domino Reaction and Central-to-Axial Chirality Conversion

Enantiodivergent one-pot synthesis of biaryls was developed using a catalytic amount of a single chiral source. A domino organocatalyst-mediated enantioselective Michael reaction and aldol condensation provided centrally chiral dihydronaphthalenes with excellent enantioselectivity, from which an enantiodivergent chirality conversion from central-to-axial chirality was achieved. Both enantiomers of biaryls were obtained with excellent enantioselectivity. All transformations can be conducted in a single reaction vessel. A plausible reaction mechanism for the enantiodivergence is proposed.

Systematic Study on the Catalytic Arsa-Wittig Reaction

Efficient catalytic arsa-Wittig reactions have been developed by using 1-phenylarsolane as a catalyst. A wide array of aldehydes was converted to the corresponding olefins in high yields with moderate to excellent E stereoselectivity in the presence of a catalytic amount of 1-phenylarsolane. Moreover, density functional theory calculations were carried out to afford insight into the E/Z selectivity.