24573-38-4

Basic information

• Product Name: 4-chlorophenolate
• Synonyms: 4-chlorophenolate
• CAS NO: 24573-38-4
• Molecular Weight: 127.55
• Mol File: 24573-38-4.mol
• Article Data: 25

Chemical Properties

• CAS DataBase Reference: 4-chlorophenolate(CAS DataBase Reference)
• NIST Chemistry Reference: 4-chlorophenolate(24573-38-4)
• EPA Substance Registry System: 4-chlorophenolate(24573-38-4)

Safety Data

• Hazardous Substances Data: 24573-38-4(Hazardous Substances Data)

Upstream product

• 3148-13-8 4-chlorophenol radical 
• 14998-27-7 chlorite 
• 20359-73-3 4-iodophenoxide 
• 183380-33-8 4-chlorophenyl triphenylmethyl ether 
• 114444-46-1 C₁₄H₁₃NO 
• 106-48-9 4-chloro-phenol 
• 75761-87-4 p-chlorophenyl fluorene-9-carboxylate 
• 16331-64-9 ethanolate 
• 2005-08-5 4-chlorophenyl benzoate 
• 115142-01-3 uridine 3'-(4-chlorophenyl) phosphate 
• 110-86-1 pyridine 
• 135263-40-0 4-chlorophenyl bis(4-methoxyphenyl) phosphate 
• 504-24-5 4-aminopyridine 
• 288-32-4 1H-imidazole 

Downstream Products

• 126083-71-4 (2,2',4,4',6,6'-hexanitro-diphenyl)-methyl anion 
• 3148-13-8 4-chlorophenol radical 
• 20359-73-3 4-iodophenoxide 
• 100-02-7 4-nitro-phenol 
• 128886-84-0 p-Chlorophenyl p-nitrobenzenesulphonate 
• 14998-27-7 chlorite 
• 7700-27-8 4-chlorophenyl benzyl ether 
• 6961-42-8 4-chlorophenyl 4-chlorobenzoate 
• 14609-74-6 p-nitrophenolate 
• 2005-08-5 4-chlorophenyl benzoate 
• 67059-81-8 4-chlorophenyl 3-chloro-benzoate 
• 29558-84-7 4-chlorophenyl 4-methoxybenzoate 
• 876-27-7 4-chlorophenyl acetate 
• 1163712-03-5 C₃H₉BP^(1-) 

Relevant articles and documents

Kinetic study on aminolysis of aryl X-substituted-cinnamates in acetonitrile: Differential medium effect determines reactivity and reaction mechanism

A kinetic study on nucleophilic substitution reactions of 2,4-dinitrophenyl X-substituted-cinnamates (1a-1f) and Y-substituted-phenyl cinnamates (2a-2g) with a series of alicyclic secondary amines in MeCN at 25.0 ± 0.1 °C is reported. The Br?nsted-type pl

Kinetic study on alkaline hydrolysis of Y-substituted phenyl picolinates: Effects of modification of nonleaving group from benzoyl to picolinyl on reactivity and reaction mechanism

Second-order rate constants (kOH-) for alkaline hydrolysis of Y-substituted phenyl picolinates (6a-6i) have been measured spectrophotometrically. A linear Bronsted-type plot is obtained with βlg = -0.34, which is typical for reactions reported previously to proceed through a stepwise mechanism with formation of an addition intermediate being the rate-determining step (RDS). However, σYo constants result in a much poorer Hammett correlation than σY- constants. Furthermore, the Yukawa-Tsuno plot exhibits an excellent linear correlation with ρY = 0.82 and r = 0.72, indicating that a negative charge develops partially on the O atom of the leaving group in the RDS. Thus, the reactions have been concluded to proceed through a forced concerted mechanism with a highly unstable intermediate 7. Comparison of the current kinetic data with those reported previously for the corresponding reactions of Y-substituted phenyl benzoates has revealed that modification of the nonleaving group from benzoyl to picolinyl causes not only an increase in reactivity but also a change in the reaction mechanism (i.e., from a stepwise mechanism to a forced concerted pathway).

Structure and mechanism of PhnP, a phosphodiesterase of the carbon-phosphorus lyase pathway

PhnP is a phosphodiesterase that plays an important role within the bacterial carbon-phosphorus lyase (CP-lyase) pathway by recycling a "dead-end" intermediate, 5-phospho-α-d-ribosyl 1,2-cyclic phosphate, that is formed during organophosphonate catabolism