74104-89-5

Basic information

• Product Name: 2-Pyridinecarboxylic acid, 4-nitrophenyl ester
• Synonyms: picolinic acid 4-nitrophenyl ester;p-nitrophenol picolinate;4-nitrophenyl pyridine-2-carboxylate;p-nitrophenyl picolinate;4-nitrophenyl picolinate
• CAS NO: 74104-89-5
• Molecular Formula: C12H8N2O4
• Molecular Weight: 244.207
• Mol File: 74104-89-5.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: 2-Pyridinecarboxylic acid, 4-nitrophenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Pyridinecarboxylic acid, 4-nitrophenyl ester(74104-89-5)
• EPA Substance Registry System: 2-Pyridinecarboxylic acid, 4-nitrophenyl ester(74104-89-5)

Safety Data

• Hazardous Substances Data: 74104-89-5(Hazardous Substances Data)

Upstream product

• 29745-44-6 pyridine-2-carbonyl chloride 
• 100-02-7 4-nitro-phenol 
• 39901-94-5 2-picolinoyl chloride hydrochloride 
• 98-98-6 2-Picolinic acid 
• 538-75-0 dicyclohexyl-carbodiimide 

Downstream Products

• 100-02-7 4-nitro-phenol 
• 158276-23-4 N^α-picolinoyllysine 
• 98-98-6 2-Picolinic acid 
• 2524-52-9 ethyl-2-picolinate 
• 39639-98-0 piperazin-1-yl(pyridin-2-yl)methanone 
• 26838-86-8 pyridine-2-carboxylic acid phenyl ester 
• 64301-94-6 2-picolinic acid 4-chlorophenyl ester 
• 22113-51-5 p-cresolate 
• 3229-70-7 phenolate 
• 24573-38-4 4-chlorophenolate 
• 18938-14-2 3-chlorophenoxide 
• 18938-16-4 4-hydroxy-benzoic acid ethyl ester; deprotonated form 
• 261172-44-5 4-acetylphenoxide 
• 14609-76-8 4-cyanophenolate 

Relevant articles and documents

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Kinetic and mechanistic studies on quinuclidinolysis of Y-substituted-phenyl picolinates: Effect of amine nature on reactivity and transition- state structure

Second-order rate constants (kN) have been measured spectrophotometrically for reactions of Y-substitutedphenyl picolinates (7a-7i) with a series of quinuclidines in 80 mol% H2O/20 mol% DMSO at 25.0 ± 0.1 °C. The Bronsted-type plot f

Aminolysis of aryl ester using tertiary amine as amino donor via c-o and c-n bond activations

An aminolysis reaction between various aryl esters and inert tertiary amines by C-O and C-N bond activations has been developed for the selective synthesis of a broad scope of tertiary amides under neutral and mild conditions. The mechanism may undergo the two key steps of oxidative addition of acyl C-O bond in parent ester and C-N bond cleavage of tertiary amine via an iminium-type intermediate.