24702-26-9

Basic information

• Product Name: 4-methyl-N-[methyl(4-methylphenyl)-lambda~4~-sulfanylidene]benzenesulfonamide
• CAS NO: 24702-26-9
• Molecular Formula: C₁₅H₁₇NO₂S₂
• Molecular Weight: 307.431
• Mol File: 24702-26-9.mol
• Article Data: 21

Chemical Properties

• Boiling Point: 479.9°C at 760 mmHg
• Flash Point: 244°C
• Density: 1.22g/cm³
• Vapor Pressure: 6.62E-09mmHg at 25°C
• Refractive Index: 1.606
• CAS DataBase Reference: 4-methyl-N-[methyl(4-methylphenyl)-lambda~4~-sulfanylidene]benzenesulfonamide(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methyl-N-[methyl(4-methylphenyl)-lambda~4~-sulfanylidene]benzenesulfonamide(24702-26-9)
• EPA Substance Registry System: 4-methyl-N-[methyl(4-methylphenyl)-lambda~4~-sulfanylidene]benzenesulfonamide(24702-26-9)

Safety Data

• Hazardous Substances Data: 24702-26-9(Hazardous Substances Data)

Upstream product

• 10486-08-5 sodium p-thiocresolate 
• 127-65-1 chloroamine-T 
• 64693-05-6 (RS)-Dimethyl-(1-methylpropyl)-sulfonium-4-methylbenzolsulfonat 
• 623-13-2 4-methylphenyl methylsulfide 
• 144-86-5 N-chloro-4-methylbenzenesulfonamide 
• 5056-07-5 (S)-methyl p-tolyl sulfoxide 
• 4104-47-6 N-sulfinyl-p-toluenesulfonamide 
• 55962-05-5 [N-(p-tolylsulfonyl)imino]phenyliodinane 
• 70-55-3 toluene-4-sulfonamide 
• 71996-32-2 N-(5λ⁴-dibenzo[b,d]thiophen-5-ylidene)-4-methylbenzenesulfonamide 
• 1240327-54-1 2-(tert-butylsulfonyl)-5-tert-butyl-(tosyliminoiodo)benzene 
• 941-55-9 4-toluenesulfonyl azide 
• 242461-31-0 [N-(p-toluenesulfonyl)imino](2-tert-butylsulfonyl)phenyliodinane 
• 4547-64-2 4-methoxybenzenesulfonyl azide 

Downstream Products

• 58044-92-1 S-methyl-S-(4-tolyl)sulfilimine 
• 623-13-2 4-methylphenyl methylsulfide 
• 28832-82-8 S-methyl-S-p-tolyl-N-(p-tolylsulfonyl)sulfoximine 
• 70-55-3 toluene-4-sulfonamide 
• 20414-85-1 S-methyl-S-(p-tolyl)sulfoximine 
• 140687-75-8 2-(3,4-dimethoxyphenyl)oxirane 
• 20520-50-7 (R)-S-methyl-S-(4-tolyl)-N-(p-tolylsulfonyl)sulfoximine 
• 20780-53-4 (R)-Styrene oxide 
• 20780-54-5 (S)-styrene oxide 
• 96-09-3 styrene oxide 

Relevant articles and documents

Can chloramine-T be a nitrene transfer agent?

Reaction of chloramine-T and methyl p-tolyl sulfide to give the corresponding sulfimide appears to proceed via a nitrene transfer mechanism in the presence of a copper(I) catalyst and a second nitrogen ligand.

Sulfonylimino group transfer reaction using imino-λ3-iodanes with I2 as catalyst under metal-free conditions

A new practical procedure of imination for sulfide has been developed. The treatment of (N-tosylimino)-phenyl-λ3-iodane, PhINTs, with various sulfides in the presence of a catalytic amount of I2 under metal-free conditions affords the corresponding N-tosylsulfilimine compounds with moderate to good yields. This facile transfer procedure of the sulfonylimino group can also be applied to triphenylphosphine to produce the respective iminotriphenylphosphoranes in high yields. According to the reaction mechanism studies, the process of imination from (N-tosylimino)-phenyl-λ3-iodane to sulfide under the conditions may involve radical steps within the reaction mechanism.

Tripodal S-Ligand Complexes of Copper(I) as Catalysts for Alkene Aziridination, Sulfide Sulfimidation, and C-H Amination

Copper(I) complexes of tris(thioimidazolyl)borates (R′TmR), including [Cu(TmPh)(PR″3)] (R″ = Ph, Cu1; Cy, Cu2) and [Cu(R′TmPh)(PR″3)]+ (R′ = N-methylimidazole; R″ = Ph, Cy) were prepared an