25654-31-3

Basic information

• Product Name: cannabigerol
• Synonyms: cannabigerol;2-[(2E)-3,7-Dimethyl-2,6-octadienyl]-5-pentylresorcinol;2-[(E)-3,7-Dimethyl-2,6-octadienyl]-5-pentyl-1,3-benzenediol;1,3-Benzenediol, 2-[(2E)-3,7-diMethyl-2,6-octadien-1-yl]-5-pentyl-;(E)-2-(3,7-DiMethyl-2,6-octadienyl)-5-pentyl-1,3-benzenediol;(E)-2-(3,7-DiMethyl-2,6-octadienyl)-5-pentylresorc;2-[(2E)-3,7-DiMethyl-2,6-octadien-1-yl]-5-pentyl-1,3-benzenediol;2-[(2E)-3,7-DiMethyl-2,6-octadienyl]-5-pentyl-1,3-benzenediol
• CAS NO: 25654-31-3
• Molecular Formula: C₂₁H₃₂O₂
• Molecular Weight: 316.4776
• Mol File: 25654-31-3.mol
• Article Data: 20

Chemical Properties

• Melting Point: 49-50 °C
• Boiling Point: 470.4°Cat760mmHg
• Flash Point: 9℃
• Appearance: /
• Density: 0.987g/cm³
• Vapor Pressure: 1.8E-09mmHg at 25°C
• Refractive Index: 1.535
• Storage Temp.: -20°C
• PKA: 9.71±0.40(Predicted)
• CAS DataBase Reference: cannabigerol(CAS DataBase Reference)
• NIST Chemistry Reference: cannabigerol(25654-31-3)
• EPA Substance Registry System: cannabigerol(25654-31-3)

Safety Data

• RIDADR: UN1230 - class 3 - PG 2 - Methanol, solution
• WGK Germany: 1
• Hazardous Substances Data: 25654-31-3(Hazardous Substances Data)

Usage

Description

Cannabigerol (CRM) (Item No. 20164) is a certified reference material categorized as a phytocannabinoid. This product is intended for research and forensic applications.

Uses

Cannabigerol is a partial agonist of CB2 and CB1 receptors (Ki values are 337 and 440 nM respectively). Cannabigerol also exhibits α2-adrenoceptor agonist activity (EC50 = 0.2 nM in mouse brain membra nes).

Definition

ChEBI: A natural product found in Cannabis sativa and Helichrysum species.

General Description

A non-psychoactive cannabinoid found in Cannabis, Cannabigerol (CBG) reportedly has efficacy for medical conditions such as glaucoma and inflammatory bowel disease. This Certified Spiking Solution? is suitable for cannabigerol testing methods by HPLC, GC/MS or LC-MS/MS for forensic analysis, clinical toxicology, urine drug testing, and Cannabis potency or impurity profiling testing applications. Cerilliant solution Certified Reference Materials (CRMs) of cannabinoids are supplied in a convenient, quantitative, US DEA-exempt solution format and with TK#s for Canadian customers.

InChI:InChI=1/C21H32O2/c1-5-6-7-11-18-14-20(22)19(21(23)15-18)13-12-17(4)10-8-9-16(2)3/h9,12,14-15,22-23H,5-8,10-11,13H2,1-4H3/b17-12+

Synthetic route

Geraniol (106-24-1) + Olivetol (500-66-3) → 2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3)

Conditions	Yield
With toluene-4-sulfonic acid In chloroform at 20℃; for 12h; Darkness;	80%
With toluene-4-sulfonic acid In chloroform at 20℃; for 12h; Darkness;	39.9%
With toluene-4-sulfonic acid In chloroform at 20℃; for 12h; Darkness;	39.9%

(E)-8-(3,7-dimethylocta-2,6-dien-1-yl)-7-hydroxy-2,2-dimethyl-5-pentyl-4H-benzo[d][1,3]dioxin-4-one → 2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3)

Conditions	Yield
With water; potassium hydroxide In 1,4-dioxane at 120℃; for 18h; Sealed tube;	64%

Geraniol (106-24-1) + Olivetol (500-66-3) → 2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3) + C31H48O2

Conditions	Yield
With aluminum oxide In 1,2-dichloro-ethane for 6h; Solvent; Reflux;	A 62% B 10 %Spectr.

4,6-dibromocannabigerol → 2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3)

Conditions	Yield
With sodium L-ascorbate; triethylamine; sodium sulfite In methanol; water at 75℃; for 24h;	5.95%

(E)-3-(3,7-dimethylocta-2,6-dien-1-yl)-2,4-dihydroxy-6-pentylbenzoic acid methyl ester (63953-93-5) → 2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3)

Conditions	Yield
With sodium hydroxide In methanol

geranyl diphosphate (763-10-0) + Olivetol (500-66-3) → C21H32O2 (55854-24-5) + 2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3)

Conditions	Yield
With Tris-HCl buffer; magnesium chloride at 25℃; pH=9.0; Enzyme kinetics;
With Tris-HCl buffer; magnesium chloride at 25℃; pH=9.0;

C22H32O3 → 2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3)

Conditions	Yield
Multi-step reaction with 3 steps 1: potassium carbonate 2: potassium hydroxide; water / methanol 3: potassium hydroxide; water / methanol / Heating View Scheme
Multi-step reaction with 4 steps 1: alkaline condition 2: aminosulfonic acid; water / tetrahydrofuran; dimethyl sulfoxide 3: potassium hydroxide; water / methanol 4: potassium hydroxide; water / methanol / Heating View Scheme

C26H36O5 → 2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3)

Conditions	Yield
Multi-step reaction with 3 steps 1: aminosulfonic acid; water / tetrahydrofuran; dimethyl sulfoxide 2: potassium hydroxide; water / methanol 3: potassium hydroxide; water / methanol / Heating View Scheme

C26H36O6 → 2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3)

Conditions	Yield
Multi-step reaction with 2 steps 1: potassium hydroxide; water / methanol 2: potassium hydroxide; water / methanol / Heating View Scheme

CBGA (25555-57-1) → 2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3)

Conditions	Yield
With water; potassium hydroxide In methanol Heating;

C22H32O3 → 2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3)

Conditions	Yield
Multi-step reaction with 4 steps 1: florisil 2: potassium carbonate 3: potassium hydroxide; water / methanol 4: potassium hydroxide; water / methanol / Heating View Scheme
Multi-step reaction with 5 steps 1: florisil 2: alkaline condition 3: aminosulfonic acid; water / tetrahydrofuran; dimethyl sulfoxide 4: potassium hydroxide; water / methanol 5: potassium hydroxide; water / methanol / Heating View Scheme

Geraniol (106-24-1) + Olivetol (500-66-3) → C21H32O2 (55854-24-5) + 2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3)

Conditions	Yield
With toluene-4-sulfonic acid In chloroform at 55℃; for 5h; Temperature; Solvent; Reagent/catalyst;

Geraniol (106-24-1) + Olivetol (500-66-3) → C21H32O2 (55854-24-5) + 2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3) + C31H48O2

Conditions	Yield
With toluene-4-sulfonic acid In chloroform at 20℃; for 12h; Solvent; Darkness;	A 280 mg B 420 mg C 712 mg

trans-geranyl bromide (6138-90-5) → 2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3)

Conditions	Yield
Multi-step reaction with 2 steps 1: potassium phosphate; methanesulfonic acid(2-dicyclohexylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II) / water; butan-1-ol / 18 h / 60 °C / Sealed tube 2: methanesulfonic acid / methanol; diethyl ether / 4 °C / Sealed tube View Scheme

trans-geranyl bromide (6138-90-5) + Olivetol (500-66-3) → 2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3)

Conditions	Yield
With potassium carbonate In tert-butyl methyl ether at 20℃; Reagent/catalyst; Solvent;

1,3-bis(methoxymethyl ether)cannabigerol → 2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3)

Conditions	Yield
With methanesulfonic acid In methanol; diethyl ether at 4℃; Sealed tube;

1,3-bis[2-(trimethylsiloxy)methoxyethyl]cannabigerol → 2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3)

Conditions	Yield
With methanesulfonic acid In methanol; diethyl ether at 4℃; Sealed tube;

C29H55BO6Si2 → 2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3)

Conditions	Yield
Multi-step reaction with 2 steps 1: potassium phosphate; methanesulfonic acid(2-dicyclohexylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II) / water; butan-1-ol / 18 h / 60 °C / Sealed tube 2: methanesulfonic acid / methanol; diethyl ether / 4 °C / Sealed tube View Scheme

1,3-Bis(methoxymethoxy)-5-pentylbenzene (94450-80-3) → 2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3)

Conditions	Yield
Multi-step reaction with 3 steps 1.1: N-ethyl-N,N-diisopropylamine; n-butyllithium / tetrahydrofuran; hexane / 1 h / 0 °C / Sealed tube 1.2: 0 - 20 °C / Sealed tube 1.3: 0.5 h 2.1: tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran / 17 h / 80 °C / Sealed tube 3.1: methanesulfonic acid / methanol; diethyl ether / 4 °C / Sealed tube View Scheme

3,7-dimethylocta-1,6-dien-3-ol (78-70-6) + Olivetol (500-66-3) → 2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3) + abnormal-CBG

Conditions	Yield
With MP-TsOH resin In ethyl acetate Flow reactor; Overall yield = 40 percent;	A 35 mg B 35 mg

2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3) + magnesium methyl carbonate (4861-79-4) → CBGA (25555-57-1)

Conditions	Yield
In N,N-dimethyl-formamide at 120℃; for 1h;	90%
In N,N-dimethyl-formamide at 120℃; for 1h;
In N,N-dimethyl-formamide at 120℃; for 1h;
In N,N-dimethyl-formamide at 130℃; for 3h;

carbon dioxide (124-38-9) + 2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3) + magnesium methanolate (109-88-6, 16436-83-2, 16436-85-4) → CBGA (25555-57-1)

Conditions	Yield
In N,N-dimethyl-formamide at 50℃; for 3h; Sealed tube;	90%
Stage #1: carbon dioxide; 2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol; magnesium methanolate at 50℃; for 3h; Sealed tube; Stage #2: With hydrogenchloride; water In methanol; chloroform pH=2;	37.5%

2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3) → 2-(3,7-dimethylocta-1,6-dienyl)-5-pentylresorcinol (95543-71-8)

Conditions	Yield
With N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium In hexane at 50℃; for 1h;	80%

2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3) → cannabigeroquinone

Conditions	Yield
With n-butyllithium; oxygen In N,N,N,N,N,N-hexamethylphosphoric triamide; hexane at 50℃; for 2h; Cooling with ice;	62%
With potassium tert-butylate; oxygen In toluene at 20℃; for 2h;	53%
With stabilized 1-hydroxy-1λ5,2-benziodoxole-1,3-dione, SIBX In ethyl acetate at 20℃; for 18h; Cooling with ice;	37%

2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3) + tert-butyldimethylsilyl chloride (18162-48-6) → C27H46O2Si

Conditions	Yield
With 1H-imidazole In dichloromethane at 20℃;	52%

2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3) + methyl iodide (74-88-4) → cannabigerol monomethyl ether (29106-17-0) + 1,3-bis(methoxy)cannabigerol (29106-16-9)

Conditions	Yield
With potassium carbonate In N,N-dimethyl-formamide for 3h;	A 35% B 40%

carbon dioxide (124-38-9) + 2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3) → CBGA (25555-57-1)

Conditions	Yield
With magnesium methanolate at 50℃; for 3h; Reagent/catalyst; Temperature; Sealed tube;	37.5%
With magnesium methanolate at 50℃; for 3h; Sealed tube;

2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3) → CBGA (25555-57-1)

Conditions	Yield
With carbon dioxide; magnesium methanolate In methanol; chloroform at 50℃; for 3h; Reagent/catalyst; Solvent; Temperature; Sealed tube;	37.5%

2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3) → 3,3'-bis((E)-3,7-dimethyl-octa-2,6-dienyl)-4,4'-dihydroxy-6,6'-dipentyl-1,1'-bi(cyclohexa-3,6-diene)-2,2',5,5'-tetraone

Conditions	Yield
With sodium hydride In toluene for 12h;	24%

2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3) → cyclocannabigerol A + cyclocannabigerol B + iodocyclocannabigerol A + spirocannabigerol A + spirocannabigerol B + C28H40O2

Conditions	Yield
With iodine In toluene for 5h; Reflux;	A 2.3% B 8.1% C 14.8% D 0.7% E 1.3% F 3.2%

diazomethane (186581-53-3, 908094-01-9) + 2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3) → cannabigerol monomethyl ether (29106-17-0)

Conditions	Yield
In methanol

2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3) → cannabichromene (20675-51-8, 4993-99-1)

Conditions	Yield
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In 1,4-dioxane for 1h; Ambient temperature;

2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3) → 6-(3,7-dimethyl-octa-2,6-dienyl)-5-hydroxy-3-pentyl-2-ethylamino-[1,4]benzoquinone

Conditions	Yield
Multi-step reaction with 2 steps 1: potassium tert-butylate; oxygen / toluene / 2 h / 20 °C 2: oxygen / water; ethanol / 2 h / 20 °C View Scheme

2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3) → 6-(3,7-dimethyl-octa-2,6-dienyl)-5-hydroxy-3-pentyl-2-pentylamino-[1,4]benzoquinone

Conditions	Yield
Multi-step reaction with 2 steps 1: potassium tert-butylate; oxygen / toluene / 2 h / 20 °C 2: oxygen / ethanol / 22 h / 20 °C View Scheme

2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3) → 6-(3,7-dimethyl-octa-2,6-dienyl)-5-hydroxy-3-pentyl-2-isobutylamino[1,4]benzoquinone

Conditions	Yield
Multi-step reaction with 2 steps 1: potassium tert-butylate; oxygen / toluene / 2 h / 20 °C 2: oxygen / ethanol / 8 h / 20 °C View Scheme

2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3) → 6-(3,7-dimethyl-octa-2,6-dienyl)-5-hydroxy-3-pentyl-2-butylamino [1,4]benzoquinone

Conditions	Yield
Multi-step reaction with 2 steps 1: potassium tert-butylate; oxygen / toluene / 2 h / 20 °C 2: oxygen / ethanol / 18 h / 20 °C View Scheme

2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3) → 2-(3,7-dimethyl-octa-2,6-dienyl)-3-hydroxy-6-methylamino-5-pentyl-[1,4]benzoquinone

Conditions	Yield
Multi-step reaction with 2 steps 1: potassium tert-butylate; oxygen / toluene / 2 h / 20 °C 2: oxygen / ethanol / 6 h / 20 °C View Scheme

2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3) → 2-(3,7-dimethyl-octa-2,6-dienyl)-3-hydroxy-6-isopropylamino-5-pentyl-[1,4]benzoquinone

Conditions	Yield
Multi-step reaction with 2 steps 1: potassium tert-butylate; oxygen / toluene / 2 h / 20 °C 2: oxygen / ethanol / 18 h / 20 °C View Scheme

2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3) → 2-benzylamino-6-(3,7-dimethyl-octa-2,6-dienyl)-5-hydroxy-3-pentyl-[1,4]benzoquinone

Conditions	Yield
Multi-step reaction with 2 steps 1: potassium tert-butylate; oxygen / toluene / 2 h / 20 °C 2: oxygen / ethanol / 18 h / 20 °C View Scheme

2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3) → 2-(3,7-dimethyl-octa-2,6-dienyl)-6-(2,2-dimethyl-propylamino)-3-hydroxy-5-pentyl-[1,4]benzoquinone

Conditions	Yield
Multi-step reaction with 2 steps 1: potassium tert-butylate; oxygen / toluene / 2 h / 20 °C 2: oxygen / ethanol / 18 h / 20 °C View Scheme

2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3) → cannabidiolic acid (1244-58-2) + cannabichromenic acid

Conditions

Yield

Multi-step reaction with 2 steps 1: N,N-dimethyl-formamide / 1 h / 120 °C 2: 2-hydroxypropyl–β–cyclodextrin; MKCSTFSFWFVCKIIFFFFSFNIQTSIANPENFLKCFSQYIPNNATNLKLVYTQNPLYMSVLNSTIHNLRFTSDTTPKPLVIVTPSHVSHIQGTILCSKKVGLQIRTSGGHDSEGMSYISQFVIVDLRNMRSIKIDVHSQTAWVEAGATLGEVYYWVNEKNENLSLAAGYCPTVCAGGHFGGGGYGPLMRNYGLAADNIIDAHLWWGKVLDRKSMGEDLFWALRGGGAESFGIIVAWKIPLVAKSTMFSVKKIMEIHELVKLVNKWQNIAYKYDKDLLLMTHFITRNITDNQGKNKTAIHTYFSSWLGGVDSLVDLMNKSFPELGIKKTDCRQLSWIDTIIFYSGVVNYDTDNFNKEILLDRSAGQNGAFKIKLDYVKKPIPESWVQILEKLYEEDIGAGMYALYPYGGIMDEISESAIPFPHRAGILYELWYICSWEKQEDNEKHLNWIRNNFMTPYVSKNPRLAYLNYRDLDIGINDPKNPNNYTQARIWGEKGKNFDRLVKVKTLVDPNNFFRNEQSIPPLPRHRH / aq. phosphate buffer / 8 h / 30 °C / pH 4.2 / Large scale; Enzymatic reaction View Scheme

2-[(2E)-3,7-dimethylocta-2,6-dienyl]-5-pentyl-benzene-1,3-diol (25654-31-3) → cannabichromenic acid

Conditions	Yield
Multi-step reaction with 2 steps 1.1: 3 h / 50 °C / Sealed tube 1.2: pH 2 2.1: 2-hydroxypropyl–β–cyclodextrin; MNCSAFSFWFVCKIIFFFLSFHIQISIANPRENFLKCFSKHIPNVANPKLVYTQHDQLYMSILNSTIQNLRFISDTTPKPLVIVTPSNSHIQATCSKKVGLQTRSGGFAEGMSYISQVPFVVVDLRNMHSIKIDVHSQTAWVEAGATLGEVYYWINEKNENLSFPGGYCPTVGVGGHFSGGGYGALMRNYGLAADNIIDAFILVNVDGKVLDPKSMGEDLFWAIRGGGGENFGIIAAWKIKLVASKSTIFSVKKNMEIHGLVKLFNKWQNIAYKYDKDLVLMTHFITKNITDNHGKNKTTVHGYFSSIFHGGVDSLDLMNKSFRELGIKKTDCKELSWIDTTIFYSGVVNYNTANFKKEDLDRSAGKKTAFSIKLDYVKKPIPETAMVKILEKLYEEDVGAGMYVLYPYGGIMEEISESAIPFPHRAGFYELWYTASWEKQEDNEKHINWVRSVYNFTTPYVSQNPRLAYLNYRDLDLGKTNHASPNNYTQARWGKWGKNFNRLVKVKTKVDPN FFRNEQSIPPLPPHHH / aq. phosphate buffer / 8 h / 30 °C / pH 5 / Large scale; Enzymatic reaction View Scheme
Multi-step reaction with 2 steps 1: N,N-dimethyl-formamide / 1 h / 120 °C 2: 2-hydroxypropyl–β–cyclodextrin; MNCSAFSFWFVCKIIFFFLSFHIQISIANPRENFLKCFSKHIPNVANPKLVYTQHDQLYMSILNSTIQNLRFISDTTPKPLVIVTPSNSHIQATCSKKVGLQTRSGGFAEGMSYISQVPFVVVDLRNMHSIKIDVHSQTAWVEAGATLGEVYYWINEKNENLSFPGGYCPTVGVGGHFSGGGYGALMRNYGLAADNIIDAFILVNVDGKVLDPKSMGEDLFWAIRGGGGENFGIIAAWKIKLVASKSTIFSVKKNMEIHGLVKLFNKWQNIAYKYDKDLVLMTHFITKNITDNHGKNKTTVHGYFSSIFHGGVDSLDLMNKSFRELGIKKTDCKELSWIDTTIFYSGVVNYNTANFKKEDLDRSAGKKTAFSIKLDYVKKPIPETAMVKILEKLYEEDVGAGMYVLYPYGGIMEEISESAIPFPHRAGFYELWYTASWEKQEDNEKHINWVRSVYNFTTPYVSQNPRLAYLNYRDLDLGKTNHASPNNYTQARWGKWGKNFNRLVKVKTKVDPN FFRNEQSIPPLPPHHH / aq. phosphate buffer / 8 h / 30 °C / pH 5 / Large scale; Enzymatic reaction View Scheme

Upstream product

• 25654-25-5 2-Propanone, 1-(2-piperidinylidene)-, (1Z)- (9CI) 
• 25654-24-4 (Z)-ETHYL 2-(PIPERIDIN-2-YLIDENE)ACETATE 
• 2565-39-1 hept-6-en-3-one 
• 2565-36-8 2,2'-[methylenebis(oxy)]bisethanol 
• 25653-19-4 1-diphenoxyphosphoryloxynaphthalene 
• 25653-16-1 tris(3,5-xylyl) phosphate 
• 256530-26-4 Butanedioic acid, 2-bromo-3-hydroxy-, dimethyl ester, (2R,3S)-rel- (9CI) 
• 2565-30-2 formyl chloride 
• 256529-47-2 3-BROMOTHIOPHENE-2-CARBOTHIOAMIDE 
• 256529-43-8 2'-CHLORO-4'-(TRIFLUOROMETHOXY)ACETANILIDE 
• 256529-25-6 2,5-DIMETHYL-1-[4-(TRIFLUOROMETHYL)PHENYL]-1H-PYRROLE-3-CARBALDEHYDE 
• 256529-20-1 2-(2-PYRAZIN-2-YL-1,3-THIAZOL-4-YL)ACETIC ACID 
• 25652-68-0 11,12-Dihydro-6H-dibenz[b,f][1,4]oxazocine 
• 256526-08-6 Benzeneethanol, 2-fluoro-alpha-methyl-, (alphaS)- (9CI) 

Downstream Products

• 2565-43-7 5-allylbarbituric acid 
• 25654-51-7 (R)-N-CBZ-AZETIDINE-2-CARBOXYLIC ACID 
• 25654-52-8 (S)-N-CBZ-AZETIDINE-2-CARBOXYLIC ACID 
• 2565-47-1 N-METHYLBARBITURIC ACID 
• 25654-86-8 [(1S,4aR,5S,7aS)-1-(hexopyranosyloxy)-5-hydroxy-1,4a,5,7a-tetrahydrocyclopenta[c]pyran-7-yl]methyl (2E)-3-phenylprop-2-enoate 
• 25655-01-0 poly(methylmethacrylate-N-vinylpyrrolidone) 
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• 2565-54-0 (6Z)-6-[(butylamino)methylidene]cyclohexa-2,4-dien-1-one 
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• 2565-56-2 2-amino-N,N,N-trimethylethanaminium 
• 2565-58-4 CHLOROMETHYLPHOSPHONIC ACID 
• 25656-78-4 5-[bis(1-isocyanato-1-cyclohexa-2,4-dienyl)methyl]-5-isocyanato-cyclohexa-1,3-diene 
• 25656-90-0 CR 39 

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