257296-61-0

Basic information

• Product Name: (-)-N-((2S,3S)-3-hydroxy-1-cyclohexyl-4-pentenyl)benzamide
• CAS NO: 257296-61-0
• Molecular Weight: 287.402
• Mol File: 257296-61-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (-)-N-((2S,3S)-3-hydroxy-1-cyclohexyl-4-pentenyl)benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-N-((2S,3S)-3-hydroxy-1-cyclohexyl-4-pentenyl)benzamide(257296-61-0)
• EPA Substance Registry System: (-)-N-((2S,3S)-3-hydroxy-1-cyclohexyl-4-pentenyl)benzamide(257296-61-0)

Safety Data

• Hazardous Substances Data: 257296-61-0(Hazardous Substances Data)

Upstream product

• 257296-67-6 (4S-trans)-4,5-dihydro-4-cyclohexylmethyl-2-phenyl-5-vinyloxazoline 
• 257296-55-2 N-((2S)-5-acetoxy-1-cyclohexyl-3-butenyl)benzamide 
• 298208-82-9 (E)-(S)-4-Amino-5-cyclohexyl-pent-2-en-1-ol 
• 114371-50-5 1,1-dimethylethyl -<1-(cyclohexylmethyl)-4-hydroxy-2-butenyl>carbamate 
• 131288-67-0 (2S)-2-amino-3-cyclohexyl-1-propanol 
• 98-88-4 benzoyl chloride 
• 114371-49-2 ethyl -5-cyclohexyl-4-<<(1,1-dimethylethoxy)carbonyl>amino>-2-pentenoate 
• 129593-15-3 (-)-N-((S)-1-hydroxy-3-cyclohexylpropyl)benzamide 
• 103322-56-1 tert-butyl [(1S)-2-cyclohexyl-1-(hydroxymethyl)ethyl]carbamate 
• 98105-42-1 (S)-2-(t-butoxycarbonylamino)-3-cyclohexyl-1-propanal 
• 27527-05-5 L-cyclohexylalanine 
• 1826-67-1 vinyl magnesium bromide 
• 126832-06-2 N-benzoylcyclohexylalaninal 

Relevant articles and documents

Stereoselective intramolecular cyclization of allyl and homoallyl benzamide via π-allylpalladium complex catalyzed by Pd(0)

The transformation of acyclic allylic benzamides 4 and homoallylic benzamides 12 to vinyl oxazolines 3 is achieved in the presence of base by the catalysis and Pd(0) in high yield and with high diastereoselectivity. Especially, in the case of homoallylic benzamides 12, trans-oxazolines 3 are formed exclusively or predominantly over cis-oxazolines 8, irrespective of the composition of their stereoisomers. The reaction is believed to proceed via the same π-allylpalladium complex that arises from either primary or secondary allylic acetates. We applied this method to the syntheses of β- amino-α-hydroxy acids 1 and γ-amino-β-hydroxy acids 2, conveniently protected as oxazoline.