2591-30-2Relevant academic research and scientific papers
Synthesis and characterization of silicon-based group 14 dendrimers Si{(CH2)2Sn[(CH2)4MPh 3]3}4 (M = Ge, Sn)
Schumann, Herbert,Aksu, Yilmaz
, p. 397 - 402 (2008/10/09)
The catalytic hydrogermylation of Si(CH=CH2)4 with Ph3GeH yielded Si(CH2CH2GePh3) 4 (1). In contrast, Sn(CH=CH2)4 and Sn(CH 2CH=CH2)s
Synthesis and characterization of some organo-all-tin dendrimers with different peripheral substituents
Schumann, Herbert,Aksu, Yilmaz,Wassermann, Birgit C.
, p. 1703 - 1712 (2007/10/03)
The synthesis of the first all-tin-dendrimer Sn[(CH2) 4SnPh3]4 (2) results from complete hydrostannation of tetra(but-3-enyl)stannane (1) with triphenyltin hydride. Selective cleavage of one phenyl group from ea
1,2-Bis(organostannyl)ethanes as powerful bidentate Lewis acids. Crystal structures of (Ph2ClSnCH2)2*(Me2N)2PO and
Jurkschat, K.,Hesselbarth, F.,Dargatz, M.,Lehmann, J.,Kleinpeter, E.,et al.
, p. 259 - 271 (2007/10/02)
The synthesis of bis(organostannyl)ethanes of the types (Ph2XSnCH2)2 (1, X = Ph; 2, X = Cl; 3, X = Br; 4, X = I) and (PhX2SnCH2)2 (5, X = Br, 6, X = I) is described.The compounds have been investigated by means of 1H, 13C and 119Sn NMR spectroscopy. 2 rea
New Reagents, XX. (Triphenylstannyl)methyllithium and Analogous Trialkylstannyl Compounds, Synthesis and Reactions
Kauffmann, Thomas,Kriegesmann, Reinhard,Altepeter, Bruno,Steinseifer, Fritz
, p. 1810 - 1817 (2007/10/02)
(Triphenylstannyl)methyllithium (1a) and analogous trialkylstannyl compounds (1b, c) were synthesized by halogen-lithium exchange reactions from 3a - c.As shown by high yields, stannyl groups are capable of stabilizing a carbanionic centre. 1a reacts with aldehydes and ketones to give β-hydroxystannanes 5 which tend to form olefins.
