2591-78-8

Usage

InChI:InChI=1/C7H15NO/c1-2-3-4-5-6-8-7-9/h7H,2-6H2,1H3,(H,8,9)

Upstream product

• 592-41-6 1-hexene 
• 77287-34-4 formamide 
• 67-56-1 methanol 
• 111-26-2 hexan-1-amine 
• 201230-82-2 carbon monoxide 
• 89399-21-3 N-hexyl-4-nitrobenzamide 
• 927902-57-6 1-hexyl-3-methylimidazolium dicyanamide 
• 34825-70-2 hex-5-en-1-amine 
• 124-38-9 carbon dioxide 
• 64-18-6 formic acid 
• 646-14-0 1-nitrohexane 
• 92412-01-6 S-hexyl N-hexylthiocarbamate 

Downstream Products

• 35161-70-7 N-methylhexanamine 
• 15586-23-9 n-hexyl isocyanide 
• 234449-91-3 4-methyl-N-hexylbenzamide 
• 1453815-73-0 5-benzylselanyl-1-hexyl-1H-tetrazole 
• 1453815-74-1 5-[(3,5-Dinitrobenzyl)selanyl]-1-hexyl-1H-tetrazole 

Relevant academic research and scientific papers

Catalytic Hydrogenation of Thioesters, Thiocarbamates, and Thioamides

Direct hydrogenation of thioesters with H2 provides a facile and waste-free method to access alcohols and thiols. However, no report of this reaction is documented, possibly because of the incompatibility of the generated thiol with typical hydrogenation catalysts. Here, we report an efficient and selective hydrogenation of thioesters. The reaction is catalyzed by an acridine-based ruthenium complex without additives. Various thioesters were fully hydrogenated to the corresponding alcohols and thiols with excellent tolerance for amide, ester, and carboxylic acid groups. Thiocarbamates and thioamides also undergo hydrogenation under similar conditions, substantially extending the application of hydrogenation of organosulfur compounds.

Cobalt nanoparticles anchoring on nitrogen doped carbon with excellent performances for transfer hydrogenation of nitrocompounds to primary amines and N-substituted formamides with formic acid

Cobalt nanoparticles anchoring on nitrogen doped carbon derived from pyrolysis of a cobalt complex and chitosan were developed for reduction of nitrocompounds with neat formic acid to their corresponding amines or N-substituted formamides by switch of solvents. Characterization results revealed that most of the nitrogen atoms are present as graphitic N and pyridinic N as anchoring sites, and the cobalt nanoparticles are wrapped by nitrogen doped carbon layers, endowing the catalyst with excellent activity and superior reusability.

A Titanium Dioxide Supported Gold Nanoparticle Catalyst for the Selective N-Formylation of Functionalized Amines with Carbon Dioxide and Hydrogen

A TiO2-supported, gold nanoparticle catalyst was found to allow the N-formylation of various amines, including normally unreactive anilines, by using CO2 as the carbonyl source under a H2 atmosphere. A series of reducible functional groups, such as olefins, halogens, carbonyls, carbamates, and cyano moieties, were completely retained during the formylation, which proved the highly selective nature of the formylation reaction. The catalyst was also found to be reusable without any loss of activity or selectivity.

Electro-Fenton treatment of imidazolium-based ionic liquids: Kinetics and degradation pathways

In this study, the removal of five imidazolium-based ionic liquids (ILs) from water was accomplished by a heterogeneous electro-Fenton treatment. Different ILs were selected in order to study the effect of the alkyl chain length and the nature of the anion. Initially, the effect of the catalyst (iron alginate beads) dosage and current were evaluated. The results showed that the optimum conditions were attained when operating with 4.27 g of catalyst and 0.3 A, achieving degradation yields and TOC reductions higher than 95% after 90 min and 80% after 480 min, respectively. Regarding the ILs with common cations, lower degradation rates were obtained for those with longer alkyl chains, thus 1-ethyl-3-methylimidazolium dicyanamide, exhibits faster degradation than 1-hexyl-3-methylimidazolium dicyanamide and 1-butyl-3-methylimidazolium dicyanamide. In addition, the influence of the counter anions on the oxidation rate of different ILs under an electro-Fenton treatment was demonstrated, following the order: methylsulfate > dicyanamide > acetate. The Microtox ecotoxicity tests of the initial and treated samples revealed that none of the three studied ILs with shorter alkyl chain lengths showed toxicity and only 1-hexyl-3-methylimidazolium dicyanamide and 1-butyl-3-methylimidazolium dicyanamide presented toxic levels, with EC50 values of 269.85 and 47.55 mg L-1, respectively. Nonetheless, after 480 min of heterogeneous electro-Fenton treatment at 0.3 A, the toxicity of both was completely reduced. Finally, to confirm the mineralization of these compounds, the identification of several reaction intermediates in the heterogeneous electro-Fenton treatment of three ILs was assayed and a plausible degradation pathway was proposed.

HOLOGRAPHIC STORAGE MEDIUM

Disclosed herein are novel amidic nitrone and a method of manufacturing a data storage media comprising mixing the amidic nitrone, as a photochromic dye, with an organic material or an inorganic material to form a holographic composition and molding the holographic composition into holographic data storage media. Disclosed herein too is an article comprising a photochromic dye and an organic material, wherein the article is used as a data storage media. Disclosed herein too is a method for recording information comprising irradiating an article that comprises a photochromic dye, wherein the irradiation is conducted with electromagnetic energy having a wavelength of about 350 to about 1,100 nanometers; and reacting the photochromic dye.

A novel PdCl2/ZrO2-SO42- catalyst for synthesis of carbamates by oxidative carbonylation of amines

At 170°C and ca. 4.0 MPa, oxidative carbonylation of aromatic amines to synthesize corresponding carbamates over a novel PdCl2/ZrO2-SO42- catalyst could proceed with high conversion and selectivity.

Amidomercuriation: A General Addition of Amides and Related Compounds to Olefins

The addition of different carboxamides and related compounds such as urethane or urea to olefins using mercury(II) nitrate followed by sodium borohydride reduction to give the corresponding N-substituted amides, urethanes, or ureas, respectively, is described.The monoalkylated ureas, through the same amidomercuriation-demercuriation procedure, yield symmetrical and unsymmetrical N,N'-disubstituted ureas.This amidomercuriation-demercuriation process provides a new, convenient, and general method for the Markovnikov amidation of carbon-carbon double bonds.