26041-18-9Relevant articles and documents
Hyder, M. L.,Markowitz, S. S.
, p. 257 - 270 (1964)
Reinsch, H.
, p. 220 - 221 (1862)
Wight, C. A.,Willner, H.,Andrews, L.
, p. 332 - 341 (1978)
Electrochemical synthesis of organochalcogenides in aqueous medium
Ribeiro Neto, Pedro B.,Santana, Sonydelane O.,Levitre, Guillaume,Galdino, Danilo,Oliveira, Jadson L.,Ribeiro, Rogério T.,Barros, Maria E. S. B.,Bieber, Lothar W.,Menezes, Paulo H.,Navarro, Marcelo
supporting information, p. 657 - 661 (2016/02/12)
The electrochemical preparation of telluride, selenide and sulfide ions was carried out in NaOH aqueous solution, using a two compartment cell. Organochalcogenides were prepared from halogenated compounds in a two-step procedure. The monochalcogenides were obtained as the major products in good yields.
Chemical species in sulfur-ammonia solutions: Influence of amide addition
Dubois,Lelieur,Lepoutre
, p. 3032 - 3038 (2008/10/08)
The acidity of sulfur-ammonia solutions has been modified by the introduction of an alkali-metal amide, and the chemical composition of the solution has been studied by using UV-visible spectrophotometry and Raman spectroscopy. It is shown that the progressive introduction of an alkali-metal amide makes the oxidized species more oxidized and the reduced species more reduced. It is found that, in sulfur-ammonia solutions, a chemical species less oxidized than S4N- exists in solution, which is neither S7N- nor a polysulfide; it is suggested that this species is a neutral form of sulfur. It is shown that the concentration of S4N- can be increased after amide addition by a factor of about 3 for a 10-2 M solution. Other oxidized forms of sulfur that have been observed are assigned to S3N- and S2N-. Very slow kinetics are observed for the modifications of the species induced by the introduction of the alkali-metal amide.