26166-61-0Relevant academic research and scientific papers
Selective oxidative deoximation with anhydrous Ce(IV) sulfate
Asutay, Oktay,Hamarat, Nilüfer,Uludag, Nesimi,Co?kun, Necdet
, p. 3902 - 3904 (2015/06/08)
Anhydrous Ce(SO4)2 in chloroform selectively converts oximes into the parent carbonyl compounds in good yields. Hammett correlations helped to indicate a plausible mechanism for the above reaction. The formation of 1-(dinitromethyl)benzene was assumed to be a product of isonitroso hydrogen reaction with arylaldoximes.
Synthesis and Properties of Dinitromethylated Arenes. Reinvestigation of the Ponzio Reaction
Suzuku, Hitomi,Takaoka, Hiroshi,Yamamoto, Hidetoshi,Ogawa, Takuji
, p. 2927 - 2932 (2007/10/02)
Several title compounds have been prepared by the modified Ponzio procedure and their IR, 1 H and 13 C NMR data are presented.In some cases trinitromethylated arenes were obtained as a by-product.Oxidative cleavage to parent aldehydes and oxidation to carboxylic acids were the major competing reactions. 9-Anthracenecarbaldehyde oxime and 10-methyl-9-anthracenecarbaldehyde oxime reacted with nitrogen dioxide in an unexpected way, giving 10-nitro-9-anthracenecarbonitrile oxide and 10-methyl-10-nitro-9-anthrone as the respective main products.Nitration of (dinitromethyl)benzene has also been examined under various conditions.
