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Relevant academic research and scientific papers

Synthesis, crystal structures and magnetic characterization of heterodinuclear CuIIGdIII and CuIITb III Schiff base complexes

Preparation, crystal structures and magnetic properties of new heterodinuclear CuIIGdIII (1) and CuIITb III (2) complexes [CuLn(L)(NO3)2(H 2O)3MeOH]NO3·MeOH

N,N′-bis(5-bromo-2-hydroxy-3-methoxybenzylidene)-1,3-diaminopropane Cu-4f-Cu and Cu-4f complexes: Synthesis, crystal structures and magnetic properties

Synthesis, crystal structures and magnetic studies of new heterotri- and heterodinuclear complexes having general formulae [Cu2Ln(L) 2(NO3)(H2O)2](NO3) 2·3H2O (where L

Lanthanide(III) compounds with the N2O4-donor Schiff base - Synthesis, spectral, thermal, magnetic and luminescence properties

New Schiff base complexes [Ln(NO3)3H2L] (where: Ln = Gd (1), Tb (2), Dy (3), Ho (4) and Er (5), H2L = N,N′-bis(5-bromo-3-methoxysalicylidene)propylene-1,3-diamine have been synthesized and characterized using el

New mononuclear CuII and tetranuclear CuII 2-LaIII2 Schiff base complexes - Physicochemical properties

The new mononuclear inclusion compound [CuLc(H2O)] (1) and heterotetranuclear [Cu2La2(L)2(NO 3)6 (EtOH)2] (2) (L= C19H 18N2O4Br2

Synthesis, crystal structures and magnetic behavior of Ni II-4f-NiII compounds

We report here synthesis, crystal and molecular structures as well as magnetic measurement results for new heterotrinuclear Schiff base complexes having a general formula [Ni2Ln(L)2(CH3COO) 2(MeOH)2]N

Dicyanamide-intertwined assembly of two new Zn complexes based on N2O4-type pro-ligand: Synthesis, crystal networks, spectroscopic insights, and selective nitroaromatic turn-off fluorescence sensing

Two new dicyanamide bridged multinuclear Zn complexes, [Zn2(L1)(μ1,5-dca)2(μ1-dca)]n (1) and [Zn2(L2)(μ1,5-dca)2(μ1-dca)]n

Structurally diverse heterobimetallic Pb(II)-Salen complexes mechanistic notion of cytotoxic activity against neuroblastoma cancer cell: Synthesis, characterization, protein–ligand interaction profiler, and intuitions from DFT

In this work, two new heterobimetallic Pb(II) complexes, namely [Zn(L1)(η1-NCS)Pb(η1-SCN)] (1) and [Cd(L2)(η1-NCS)Pb(η1-SCN)]n (2) integrated from Salen ligands (L1/L

Pseudohalide-controlled assemblies of Copper-Schiff base complexes with an encapsulated sodium ion: Synthesis, crystal structure, and computational studies

Three new hetero-bimetallic coordination complexes [Na(Cu IIL1)2](ClO4)·0.5H 2O (1), [Na(CuIIL2)2][Cu I2(μ1,3-NCS)3]n

Series of dicyanamide-interlaced assembly of zinc-schiff-base complexes: Crystal structure and photophysical and thermal studies

Four new dicyanamide (dca) bridged multinuclear ZnII-Schiff-base complexes, {[Zn2L1(μ1,5-dca)dca] ·CH3OH}2 (1), [Zn2L2(μ 1,5-dca)dca]n (2), [Zn3L3 2(μ1,5-dca)2]n (3), and [(ZnL4)2Zn(μ1,5-dca)dca]n (4), have been synthesized using four different Schiff bases L1H 2 = N,N/-bis(3-methoxysalicylidenimino)-1,3- diaminopentane, L2H2 = N,N'-bis(5-bromo-3- methoxysalicylidenimino)-1,3-diaminopropane, L3H2 = N,N'-bis(5-bromosalicylidenimino)-1,3-diaminopropane, and L4H 2 = N,N'-bis(5-chlorosalicylidenimino)-1,3-diaminopropane and NaN(CN)2 in order to extend the metal-ligand assembly. The directional properties of linear end-to-end bridging dca ligands have resulted in different metal ion connectivities leading to unique variety of templates in each of the complexes. All the ligands and complexes have been characterized by microanalytical and spectroscopic techniques. The structures of the complexes have been conclusively determined by single crystal X-ray diffraction studies. Thermogravimetric analyses have been performed to investigate the thermal stability of the metal-organic frameworks. Finally, the photoluminescence properties of the complexes as well as their respective ligands have been investigated with a comparative approach.