26760-21-4

Basic information

• Product Name: METHYL 4-CHLOROBENZENE SULFINATE
• Synonyms: METHYL 4-CHLOROBENZENE SULFINATE
• CAS NO: 26760-21-4
• Molecular Formula: C₇H₇ClO₂S
• Molecular Weight: 190.65
• Mol File: 26760-21-4.mol
• Article Data: 18

Chemical Properties

• Appearance: /
• CAS DataBase Reference: METHYL 4-CHLOROBENZENE SULFINATE(CAS DataBase Reference)
• NIST Chemistry Reference: METHYL 4-CHLOROBENZENE SULFINATE(26760-21-4)
• EPA Substance Registry System: METHYL 4-CHLOROBENZENE SULFINATE(26760-21-4)

Safety Data

• Hazard Codes: Xi
• Hazardous Substances Data: 26760-21-4(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 100-03-8 4-chlorobenzenesulfinic acid 
• 14752-66-0 sodium p-chlorobenzenesulphinate 
• 673-41-6 p-chlorobenzenediazonium tetrafluoroborate 
• 106-54-7 p-Chlorothiophenol 
• 123-09-1 4-chlorophenyl methyl sulfide 
• 124-41-4 sodium methylate 
• 14204-31-0 2-(4-chlorophenylthio)isoindoline-1,3-dione 
• 1142-19-4 4,4'-dichlorodiphenyl disulfide 
• 79-22-1 methyl chloroformate 
• 98-60-2 4-chlorobenzenesulfonyl chloride 
• 2751-25-9 p-chlorophenylsulfonyl hydrazide 

Downstream Products

• 1044572-72-6 [4-(4-chloro-benzenesulfinyl)phenyl]dimethylamine 
• 14934-01-1 p-Chloro-N-phenylbenzenesulfinamide 
• 1300714-52-6 4-(4-chlorophenylsulfinyl)-N-methylaniline 
• 107249-49-0 1-chloro-4-((isocyanomethyl)sulfonyl)benzene 
• 105826-29-7 N-(4-Chloro-benzenesulfonylmethyl)-formamide 
• 20608-64-4 p-chlorophenyl p-methylphenyl sulfoxide 
• 15446-14-7 1-allylsulfanyl-4-chloro-benzene 
• 16096-86-9 p-chlorobenzenesulphinamide 
• 59693-95-7 (4-chlorophenyl)(cyclohexyl)sulfane 
• 1142-19-4 4,4'-dichlorodiphenyl disulfide 
• 1017238-73-1 N-allyl-4-chlorobenzenesulfinamide 
• 1017238-74-2 N-(4-chlorophenylsulfinyl)-N,N-diethylamine 
• 6419-71-2 4-chloro-N,N-diethylbenzenesulfonamide 

Relevant articles and documents

Isocyanide-Induced Esterification of Sulfinic Acids to Access Sulfinates

The isocyanide-induced esterification of sulfinic acids with alcohols or thiophenols access to sulfinates has been developed. Various primary, secondary, and tertiary alcohols could be compatible with the established protocols. Notably, such an isocyanide-induced synthetic strategy presented the advantages of simple operation, good functional group tolerance, and more than 40 examples up to 99% yields. (Figure presented.).

Direct synthesis of sulfinic esters via ultrasound accelerated tandem reaction of thiols and alcohols with N-bromosuccinimide

The direct transformation of various thiols and simple alcohols with N-bromosuccinimide into sulfinic esters has been investigated by using different categories of base/acidic catalysts as well as co-solvents under varied reaction conditions. The reaction was found out to afford the sulfinic esters with high yields in the absence of catalysts, especially within the shorter time under the acceleration of ultrasonic irradiation than under the longer-lasting conventional stirring conditions.

Efficient electrosynthesis of sulfinic esters via oxidative cross-coupling between alcohols and thiophenols

A new protocol for S O bond formation was developed by electrochemical oxidative cross-coupling between alcohols and thiophenols. With this strategy, a series of valuable sulfinic ester derivatives were synthesized up to 96% yield from basic starting materials. A preliminary mechanistic investigation reveals that this reaction involves oxygen reduction reaction (ORR).