26928-23-4

Basic information

• Product Name: Benzene, 1-chloro-4-[(1E)-2-fluoroethenyl]-
• CAS NO: 26928-23-4
• Molecular Formula: C8H6ClF
• Molecular Weight: 156.587
• Mol File: 26928-23-4.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzene, 1-chloro-4-[(1E)-2-fluoroethenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-chloro-4-[(1E)-2-fluoroethenyl]-(26928-23-4)
• EPA Substance Registry System: Benzene, 1-chloro-4-[(1E)-2-fluoroethenyl]-(26928-23-4)

Safety Data

• Hazardous Substances Data: 26928-23-4(Hazardous Substances Data)

Upstream product

• 98509-03-6 1-((E)-2-Benzenesulfonyl-2-fluoro-vinyl)-4-chloro-benzene 
• 98506-75-3 2-Benzenesulfonyl-1-(4-chloro-phenyl)-2-fluoro-ethanol 
• 104-88-1 4-chlorobenzaldehyde 
• 88691-45-6 (E)-[2-(4-chlorophenyl)ethenyl]trimethylsilane 
• 201230-82-2 carbon monoxide 
• 413614-15-0 1-bromo-1-fluoro-2-(4-chlorophenyl)ethylene 
• 28321-09-7 1-chloro-4-(2,2-difluorovinyl)benzene 

Downstream Products

• 223919-54-8 2-[(E)-2-(4-chlorophenyl)ethenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 73350-59-1 (E)-1-chloro-4-(hex-1-en-1-yl)benzene 
• 1657-50-7 (E)-1-(4-chlorophenyl)-2-phenylethene 

Relevant articles and documents

Stereodivergent hydrodefluorination of: Gem -difluoroalkenes: Selective synthesis of (Z)- and (E)-monofluoroalkenes

We have developed a novel approach for the stereodivergent hydrodefluorination of gem-difluoroalkenes using copper(i) catalysts to obtain stereodefined monofluoroalkenes. Both (Z)- and (E)-terminal monofluoroalkenes were obtained by the hydrodefluorination of gem-difluoroalkenes in the presence of copper(i) catalysts and diboron or hydrosilane, respectively, with high stereoselectivity. DFT calculations were conducted to elucidate the stereoselectivity.

Synthesis of monofluoroalkenes via Julia-Kocienski reaction

Monofluoromethyl 3,5-bis(trifluoromethyl)phenyl sulfone 1 was synthesized and employed in Julia-Kocienski fluoroolefination reaction with various ketones and aldehydes. Optimal reaction conditions were found to be the treatment of substrates with KOH or C

A Novel and Efficient Synthesis of Fluoromethyl Phenyl Sulphone and Its Use as a Fluoromethyl Wittig Equivalent

A new synthesis of fluoromethyl phenyl sulphone (2) and the reaction of its conjugate base (3) with carbonyl compounds provides β-fluoro-alcohols (5), which are utilized to prepare terminal vinyl fluorides (8) via α-fluoro-α,β-unsaturated sulphones (6).