88691-45-6

Basic information

• Product Name: Silane, [2-(4-chlorophenyl)ethenyl]trimethyl-, (Z)-
• CAS NO: 88691-45-6
• Molecular Formula: C11H15ClSi
• Molecular Weight: 210.779
• Mol File: 88691-45-6.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: Silane, [2-(4-chlorophenyl)ethenyl]trimethyl-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [2-(4-chlorophenyl)ethenyl]trimethyl-, (Z)-(88691-45-6)
• EPA Substance Registry System: Silane, [2-(4-chlorophenyl)ethenyl]trimethyl-, (Z)-(88691-45-6)

Safety Data

• Hazardous Substances Data: 88691-45-6(Hazardous Substances Data)

Upstream product

• 16116-78-2 (4-bromophenyl)(trimethylsilyl)acetylene 
• 78704-49-1 1-(4-chlorophenyl)-2-trimethylsilylacetylene 
• 637-87-6 1-Chloro-4-iodobenzene 
• 18107-18-1 diazomethyl-trimethyl-silane 
• 1073-67-2 4-vinylbenzyl chloride 
• 75-77-4 chloro-trimethyl-silane 
• 754-05-2 ethenyltrimethylsilane 
• 336193-47-6 2-chloro-1-(4-chloro-phenyl)-2-trimethylsilanyl-ethanol 
• 104-88-1 4-chlorobenzaldehyde 
• 336193-39-6 2-chloro-1-(4-chlorophenyl)-2-(trimethylsilyl)ethyl acetate 
• 16029-98-4 trimethylsilyl iodide 
• 873-73-4 4-n-chlorophenylacetylene 

Downstream Products

• 168006-99-3 (E)-1-chloro-4-(2-iodovinyl)benzene 
• 247217-76-1 3-acetoxy-1-(4-chlorophenyl)-2-trimethylsilylpropene 
• 1104997-38-7 (E)-(3-(4-chlorophenyl)prop-2-ene-1,1-diyl)dibenzene 
• 66482-29-9 1-[(E)-2-bromoethenyl]-4-chlorobenzene 
• 1073-67-2 4-vinylbenzyl chloride 
• 30626-03-0 (3E)-4-(4-chlorophenyl)-3-buten-2-one 
• 26928-24-5 (Z)-1-chloro-4-(2-fluorovinyl)benzene 
• 26928-23-4 (E)-1-chloro-4-(2-fluorovinyl)benzene 
• 24721-26-4 4-chlorochalcone 

Relevant articles and documents

Asymmetric Hydrosilylation of β-Silyl Styrenes Catalyzed by a Chiral Palladium Complex

A palladium complex coordinated with a chiral SIPHOS ligand was evaluated as an efficient catalyst for asymmetric hydrosilylation of β-silyl styrenes with trichlorosilane and 23 1,2-bis(silyl) chiral compounds were produced. Good to excellent enantioselec

Stereoselective Transfer Semi-Hydrogenation of Alkynes to E-Olefins with N-Heterocyclic Silylene–Manganese Catalysts

The synthesis and structures of the first SiII-donor supported manganese(II) complexes [L1]MnCl2, [L2]MnCl2, and [L3]2MnCl2 are reported, bearing a pincer-type bis(NHSi)-pyridine ligand L1, bidentate bis(NHSi)-ferrocene ligand L2, and two monodentate NHSi ligands L3 (NHSi = N-heterocyclic silylene), respectively. They act as unprecedented very active and stereoselective Mn-based precatalysts (1 mol % loading) in transfer semi-hydrogenations of alkynes to give the corresponding E-olefins using ammonia–borane as a convenient hydrogen source under mild reaction conditions. Complex [L1]MnCl2 shows the best catalytic performance with quantitative conversion rates and excellent E-stereoselectivities (up to 98 %) for different alkyne substrates. Different types of functional groups can be tolerated, except CN, NH2, NO2, and OH groups at the phenyl group of 1-phenyl substituted alkynes.

Preparation of allyl and vinyl silanes by the palladium-catalyzed silylation of terminal olefins: A silyl-heck reaction

Installing silicon is easy! A high-yielding protocol for the palladium-catalyzed silylation of terminal alkenes is reported. This method allows facile conversion of styrenes to E-β-silyl styrenes by using iodotrimethylsilane (TMSI) or chlorotrimethylsilane/lithium iodide (see scheme). Terminal allyl silanes with good E/Z ratios are also readily accessed from α-olefins.