269399-39-5

Upstream product

• 104-53-0 3-phenyl-propionaldehyde 
• 17494-61-0 ((3-phenylpropyl)sulfonyl)benzene 
• 30134-12-4 phenyl 3-phenylpropyl sulfide 
• 69804-99-5 3-phenylpropanol methanesulfonate 
• 7484-37-9 (3-phenylpropyl)triphenylphosphonium bromide 
• 149524-96-9 2-(tert-butyldimethylsilanyloxymethyl)-3-phenylpropionaldehyde 
• 122-97-4 3-Phenyl-1-propanol 
• 886971-60-4 2-benzyl-1-[(tert-butyldimethylsilyl)oxy]-6-phenyl-3-hexene 

Downstream Products

• 886971-61-5 2-benzyl-6-phenyl-(E)-3-hexenyl acetate 
• 886971-62-6 2-benzyl-6-phenyl-(E)-3-hexenyl trifluoroacetate 
• 886971-63-7 methyl 2-benzyl-6-phenyl-(E)-3-hexenoate 

Relevant academic research and scientific papers

Peracid dependent stereoselectivity and functional group contribution to the stereocontrol of epoxidation of (E)-alkene dipeptide isosteres

Twelve Boc-protected phenylalanyl-phenylalanine and phenylalanyl-glycine trans-vinyl isosteres were epoxidised with magnesium monoperoxyphtalate hexahydrate (MMPP) and trifluoroperacetic acid, and the results have been compared with those from earlier stu

Epoxidation of peptidyl olefin isosteres. Stereochemical induction effect of chiral centers at four adjacent C(α) positions

Four tripeptidyl olefin isosteres were prepared, each of which contains a single chiral center derived from the bulky amino acid phenylalanine at positions corresponding to the P2-P'2 positions of a protease substrate. The effect of these chiral centers on the stereochemical outcome of mCPBA epoxidation of the olefin functionality was studied. A chiral center at P2 or P'2 position has no significant effect, and the P'1 position exerts a small stereoselectivity. A chiral center at the P1 position, on the other hand, has a profound chiral induction effect on the epoxidation reaction. (C) 2000 Elsevier Science Ltd.