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Usage

Uses

Used in Fragrance and Personal Care Industry:
[1-(allyloxy)ethyl]benzene is used as a key component in the fragrance and personal care industry, where it contributes to the development of scents and other formulations for products such as perfumes, lotions, and shampoos. Its unique chemical structure allows for the creation of diverse and complex fragrances.
Used in Organic Synthesis:
As a building block in organic synthesis, [1-(allyloxy)ethyl]benzene is used as a precursor for the production of various organic compounds. Its reactivity, particularly from the allyloxy group, facilitates the formation of new chemical bonds and the synthesis of a wide range of molecules.
Used in Pharmaceutical and Agrochemical Manufacturing:
[1-(allyloxy)ethyl]benzene is also utilized as a precursor in the manufacture of pharmaceuticals and agrochemicals. Its reactivity and structural properties make it a valuable starting material for the development of new drugs and agricultural chemicals.
Used in the Food Industry:
[1-(allyloxy)ethyl]benzene serves as a flavoring agent in the food industry, where it is used to enhance the taste and aroma of various products. Its unique chemical structure allows for the creation of distinct and appealing flavors.
Safety Precautions:
It is important to handle [1-(allyloxy)ethyl]benzene with care, as it may pose health risks and is flammable. Proper safety measures should be taken during its use and storage to minimize potential hazards.

InChI:InChI=1/C11H14O/c1-3-9-12-10(2)11-7-5-4-6-8-11/h3-8,10H,1,9H2,2H3

Upstream product

• 98-85-1 1-Phenylethanol 
• 107-18-6 allyl alcohol 
• 100-51-6 benzyl alcohol 
• 74-88-4 methyl iodide 
• 18146-00-4 allyloxytrimethylsilane 
• 98-86-2 acetophenone 
• 100-42-5 styrene 
• 1445-91-6 (S)-1-phenylethanol 
• 106-95-6 allyl bromide 
• 107-05-1 3-chloroprop-1-ene 

Downstream Products

• 98-85-1 1-Phenylethanol 
• 69119-38-6 (+/-)-1-phenylethyl (E)-1-propenyl ether 
• 98-86-2 acetophenone 

Relevant academic research and scientific papers

Addition of alcohols and acids to olefins in presence of zeolite catalyst H-beta

By studying the reactions of styrene and norbornene with different alcohols and carbonic acids in the presence of heterogenic catalyst, it was found that the selected zeolite H-Beta is an active and selective catalyst for these reactions. Ethers and esters of norbornene have exo-configuration. It has been established that reaction of norbornene with diols, catalyzing by zeolite Beta, leads to the formation of esters, which have not been found before.

Cationic platinum-catalyzed etherification by intra- and intermolecular dehydration of alcohols

Catalytic etherification of diols proceeds to give various cyclic ethers by use of cationic platinum salt, which is in situ prepared from PtCl2 and AgSbF6. Etherification of benzylic alcohols is also possible by intermolecular dehydration. Both of intra- and intermolecular etherifications smoothly proceed even under an atmosphere of air.

Facile and selective deallylation of allyl ethers using diphosphinidenecyclobutene-coordinated palladium catalysts

(π-Allyl)palladium triflate bearing a 1,2-bis(4-methoxyphenyl)-3,4- bis(2,4,6-tri-tert-butylphenylphosphinidene)cyclobutene ligand (DPCB-OMe), [Pd(η3-C3H5)(DPCB-OMe)]OTf, efficiently catalyzes deallylation of a variety of allyl ethers in aniline to give corresponding alcohols in high yields under mild conditions. The reactions can be performed in air without loss of a variety of functionalities including vinyl, alkynyl, hydroxy, acetoxy, silyloxy, and acetal groups. Allyl 2-allyloxybenzoate selectively undergoes deallylation of the allyloxy group to give allyl salicylate in quantitative yield.

Organic reactions catalyzed by methylrhenium trioxide: Dehydration, amination, and disproportionation of alcohols

Methylrhenium trioxide (MTO) is the first transition metal complex in trace quantity to catalyze the direct formation of ethers from alcohols. The reactions are independent of the solvents used: benzene, toluene, dichloromethane, chloroform, acetone, and in the alcohols themselves. Aromatic alcohols gave better yields than aliphatic. Reactions between two different alcohols could also be used to prepare unsymmetric ethers, the best yields being obtained when one of the alcohols is aromatic. MTO also catalyzes the dehydration of alcohols to form olefins at room temperature, aromatic alcohols proceeding in better yield. When primary (secondary) amines were used as the limiting reagent, direct amination of alcohols catalyzed by MTO gave good yields of the expected secondary (tertiary) amines at room temperature. Disproportionation of alcohols to alkanes and carbonyl compounds was also observed for aromatic alcohols in the presence of MTO. On the basis of the results of this investigation and a comparison with the interaction between MTO and water, a concerted process and a mechanism involving carbocation intermediates have been suggested.

Efficient reductive etherification of carbonyl compounds with alkoxytrimethylsilanes

An efficient TMSOTf catalyzed ether synthesis from carbonyl compounds and alkoxytrimethylsilanes via triethylsilane-reduction is described.

Elaboration of α-Substituted Benzyl Ethers and Sulphides by Suppression of the Wittig and Related Rearrangements

Co-ordination of benzyl alkyl ethers and sulphides to chromium tricarbonyl allows α-substitution via the corresponding α-carbanions to be achieved by suppression of the Wittig and related rearrangements.