27126-32-5

Upstream product

• 3376-36-1 acetone O-benzyloxime 
• 591-51-5 phenyllithium 
• 617-94-7 1-methyl-1-phenylethyl alcohol 
• 62-53-3 aniline 
• 100-42-5 styrene 
• 98-83-9 isopropenylbenzene 
• 67-56-1 methanol 
• 934-53-2 cumenyl chloride 
• 154416-02-1 4-Nitro-benzenesulfonic acid 1-methyl-1-phenyl-ethyl ester 
• 154416-01-0 4-Chloro-benzenesulfonic acid 1-methyl-1-phenyl-ethyl ester 
• 154416-00-9 Toluene-4-sulfonic acid 1-methyl-1-phenyl-ethyl ester 
• 53439-67-1 benzenesulfonic acid-(1-methyl-1-phenyl-ethyl ester) 
• 3575-19-7 2-bromo-2-phenylpropane 

Downstream Products

• 6962-10-3 4-cumyl-aniline 
• 34295-23-3 phenyl cumyl nitroxide 

Relevant academic research and scientific papers

Visible-Light-Induced Copper-Catalyzed Intermolecular Markovnikov Hydroamination of Alkenes

A visible-light-induced copper-catalyzed intermolecular hydroamination of alkenes using commercially accessible primary and secondary amines has been established. This effective method exhibits good tolerance of a broad range of functional groups and provides a facile access to an array of valuable amines with Markovnikov regioselectivity. The process can be positively expected to be used in bioactive amines, and it may provide new potential in the discovery of copper-catalyzed hydrofunctionalization reactions.

Benzyl thioether formation merging copper catalysis

A novel copper-catalyzed thioetherification reaction has been developed to afford benzyl thioethers in moderate to excellent yields. Under the mild and easy-to-operate conditions, a variety of thioethers are efficiently prepared from readily available ben

Expanding the forefront of strong organic br?nsted acids: Proton-catalyzed hydroamination of unactivated alkenes and activation of au(i) for alkyne hydroamination

The synthesis of a solid, bench-stable, strong organic Br?nsted acid with a computed pKa of 0.9 is reported. An X-ray crystal structure and DFT calculations are provided which offer insight into the bonding of this acid. The application of this

Novel one-pot synthesis of N-alkyl arylamines from oxime ethers using organometallic reagents

A novel one-pot synthesis of α,α-disubstituted secondary arylamines from oxime ethers has been developed by two separate additions of organometallic reagents. As a related arylamine construction, very efficient synthesis of N-(diallyl)methyl arylamines is

NUCLEOPHILIC SUBSTITUTION REACTIONS OF CUMYL CHLORIDES IN METHANOL

Nucleophilic substitution reactions of cumyl chlorides with anilines in methanol have been investigated.Large negative ρY+ values in methanol and weak chloride common ion rate depression support a mechanism in which a preformed benzylic-type carbocation intermediate reacts with the solvent and the added nucleophile, aniline.All positive ρX (ρnuc) values observed and the estimated non-interactive point, ?Y+ = 0.72, strongly suggest that deprotonation of a mobile proton from the nucleophile occurs during the reaction.Fair linear correlation is exhibited for the plot of stability of carbocation, as expressed by the enthalpy of cation formation (AM1), and ?Y+, indicating that the thermodynamic driving force is nearly compensated for by the intrinsic barrier.

Nucleophilic Substitution Reaction of Cumyl Arenesulfonates with Anilines

The nucleophilic substitution reaction of cumyl arenesulfonate with aniline has been investigated.The reaction in acetonitrile proceeds by the SN2 mechanism with probable frontside nucleophilic attack.The large magnitude of ρXZ (=-0.75) obtained results in an observable sign reversal of ρZ at ?'X = 0.83, with a negative ρZ value for ?X > ?'X.This rather unusual phenomenon can be rationalized by a strong interaction between the nucleophile and leaving group due to their close proximity in the transition state, which in turn is a result of the frontside nucleophilic attack.The reactions in methanol indicate that the SN1 channel competes with the SN2 pathway and ion-pair return is observed when the aniline nucleophhile concentration is low.

The Photochemically Induced Oxidation of Aniline by Hydroperoxides: An Electron Paramagnetic Resonance Study. Part II.

The oxidation reaction of aniline by tertiary hydroperoxides, induced photochemically, was studied.The peculiar radical intermediates, nitroxides and peroxy radicals, involved in the reaction mechanism were detected and identified by EPR spectroscopy.The presence of these intermediates confirm that PhNO is the first product of the oxidation of aniline and the PhNH radical as its precursor.

Antioxidant for polyester fluids - alpha - methyl - n phenylbenzenemethanamine

An antioxidant for lubricating oils comprising an amine compound selected from substituted benzylamines or a substituted 1-amino-1,2,3,4-tetrahydro-naphthalene. The preferred anti-oxidants are N-(alpha -methyl -p -octylbenzyl) aniline, N-(alpha-methylbenz