2720-67-4Relevant articles and documents
Versatile coordination environment and interplay of metal assisted secondary interactions in the organization of supramolecular motifs in new Hg(II)/PhHg(II) dithiolates
Rajput, Gunjan,Yadav, Manoj Kumar,Thakur, Tejender S.,Drew, Michael G.B.,Singh, Nanhai
, p. 225 - 233 (2014)
New mercury(II) complexes of the form [PhHg(L)] (L = L1 (1), L2 (2), L3′ (3), L4 = (4)); [Hg(L)2] (L = L5 (5), L4 (7) and [Hg 2(L6)4] (6) have been synthesized and characterized by micro analysis and X-ray crystallography. Both 1 and 2 are linear; complex 2 revealed intramolecular Hga?O bonding interactions. Complex 3 possesses T-shaped geometry in a linear polymeric chain motif. Although serendipitously formed, 3 is the first example of a metal trithioxanthate complex. 4 is a typical dimer and in 5, a helical chain motif is generated via Hga?S contacts. 6 is a dinuclear complex with distorted square pyramidal geometry. 7 is mononuclear with a tetrahedrally coordinated mercury(II) ion. All complexes are luminescent in solution and solid state. In 2 the nature of Hga?O interactions have been assessed by DFT calculations and the electronic transitions in 3 have been corroborated by TDDFT calculations.
Synthesis of nanostructured powders and thin films of iron sulfide from molecular precursors
Almanqur, Laila,Vitorica-Yrezabal, Inigo,Whitehead, George,Lewis, David J.,O'Brien, Paul
, p. 29096 - 29103 (2018/08/29)
Iron(iii) xanthate single-source precursors [Fe(S2COR)3] (R = methyl, ethyl, isopropyl and 1-propyl) were used to deposit iron sulfide thin films and nanostructures by two simple, efficient and low-cost methods (spin coating and solid state deposition). The single-crystal X-ray structures of the iron(iii) n-propyl xanthate and iron(iii) iso-propyl xanthate have been determined. Thermogravimetric analysis (TGA) studies of the complexes shows that decomposition of the complexes produces iron sulfide, pyrite or trolite. The crystallinity of iron sulfide thin films and powder samples was studied using X-ray diffraction (XRD), and their morphology was studied by scanning electron microscopy (SEM).
Copper-catalyzed synthesis of thiazol-2-yl ethers from oxime acetates and xanthates under redox-neutral conditions
Zhu, Zhongzhi,Tang, Xiaodong,Cen, Jinghe,Li, Jianxiao,Wu, Wanqing,Jiang, Huanfeng
supporting information, p. 3767 - 3770 (2018/04/17)
A novel copper-catalyzed annulation of oxime acetates and xanthates for the synthesis of thiazol-2-yl ethers with remarkable regioselectivity has been developed. Various oxime acetates, whether derived from aryl ketones or alkyl ketones, or natural product cores are suitable for this conversion. Unique dihydrothiazoles were also obtained when both reaction sites were methine. Mechanistic studies indicated that imino copper(iii) intermediates were involved. In addition, this protocol proceeded under redox-neutral conditions and did not require additives or ligands.