27353-48-6

Usage

Uses

Used in the Pharmaceutical Industry:
SG 00589 is used as a humectant and solvent for the production of various pharmaceutical formulations, such as elixirs, syrups, and suppositories. Its humectant properties help maintain the stability and shelf life of these products by preventing them from drying out.
Used in the Cosmetics and Personal Care Industry:
In the cosmetics and personal care industry, SG 00589 is used as a moisturizer, solvent, and preservative in products like lotions, creams, toothpaste, and shaving foam. Its humectant properties help retain moisture in the skin, while its solvent properties allow for the easy incorporation of other ingredients.
Used in the Food and Beverage Industry:
SG 00589 is used as a humectant, emulsifier, and sweetener in the food and beverage industry. It helps maintain the texture and moisture content of products like baked goods, confectionery, and ice cream. Additionally, it is used as a thickening agent in liquid foods and beverages.
Used in the Textile Industry:
In the textile industry, SG 00589 is used as a humectant, plasticizer, and anti-static agent in the manufacturing of fibers and fabrics. Its humectant properties help maintain the softness and flexibility of the materials, while its anti-static properties reduce the buildup of static electricity.
Used in the Automotive Industry:
SG 00589 is used as a component in the production of antifreeze and coolants for automotive applications. Its ability to lower the freezing point and raise the boiling point of water makes it an effective ingredient in these products, helping to prevent engine overheating and corrosion.
Used in the Energy Industry:
In the energy industry, SG 00589 is used as a key component in the production of biodiesel, a renewable and environmentally friendly alternative to traditional fossil fuels. It is also used as a solvent and additive in the manufacturing of various lubricants and hydraulic fluids.
Used in the Agricultural Industry:
SG 00589 is used as a humectant, solvent, and carrier in the agricultural industry for the formulation of pesticides, herbicides, and fertilizers. Its properties help improve the effectiveness and stability of these products, ensuring their proper application and absorption by plants.
Used in the Paper and Printing Industry:
In the paper and printing industry, SG 00589 is used as a humectant, plasticizer, and solvent in the manufacturing of inks, adhesives, and paper products. Its properties help improve the quality and durability of these products, as well as their resistance to environmental factors.
Used in the Plastics and Polymer Industry:
SG 00589 is used as a plasticizer, humectant, and compatibility agent in the plastics and polymer industry. Its properties help improve the flexibility, toughness, and processability of various plastics and polymers, making them more suitable for a wide range of applications.
Used in the Explosives Industry:
In the explosives industry, SG 00589 is used as a component in the formulation of various explosive materials. Its properties help improve the stability and performance of these materials, ensuring their safe and effective use in various applications.
Used in the Preparation of Potential HIV-1 Integrase Inhibitors:
SG 00589, in the form of 2-bromophenanthridone, is used in the development of potential HIV-1 integrase inhibitors. These inhibitors have the potential to play a significant role in the treatment and management of HIV/AIDS by disrupting the viral replication process.

InChI:InChI=1/C13H8BrNO/c14-8-5-6-12-11(7-8)9-3-1-2-4-10(9)13(16)15-12/h1-7H,(H,15,16)

Upstream product

• 75-44-5 phosgene 
• 5455-13-0 2-amino-5-bromobiphenyl 
• 1015-89-0 phenanthridin-6-ol 
• 40737-06-2 2-bromo-6-methylphenanthridine 
• 17337-13-2 [1,1'-biphenyl]-2-yl-isocyanate 
• 7147-52-6 N-(5-bromo-[1,1'-biphenyl]-2-yl)acetamide 
• 1015-89-0 6(5H)-phenanthridinone 
• 313268-47-2 2-iodo N-(4-bromophenyl)benzamide 
• 610-97-9 o-iodo-methyl-benzoic acid 
• 103-88-8 4-bromoacetanilide 
• 106-40-1 4-bromo-aniline 
• 2446-83-5 di-isopropyl azodicarboxylate 
• 98-80-6 phenylboronic acid 
• 66416-72-6 4-bromo-2-iodoaniline 

Downstream Products

• 107917-50-0 6-hydroxy-phenanthridine-2-carboxylic acid 
• 1015-89-0 6(5H)-phenanthridinone 
• 38088-96-9 2-methoxyphenanthridin-6(5H)-one 
• 38052-80-1 2-bromo-6-chlorophenanthridine 

Relevant academic research and scientific papers

ORGANIC LIGHT-EMITTING DEVICE

An organic white light-emitting device comprising an anode, a cathode and at least one light-emitting layer between the anode and the cathode, wherein a first light-emitting layer comprises a first light-emitting compound of formula (I): wherein R1, R2 and R3 independently in each occurrence is a substituent; M1 is a transition metal; L1 is a ligand other than a ligand of formula: (II) a and b are each 0 or a positive integer; x is at least 1; and y is 0 or a positive integer, a light-emitting layer of the device comprising at least one further light-emitting material.

Application of phenanthridine compounds to pesticides

The invention relates to an application of phenanthridine compounds shown in general formula (1) to pesticides. Part of the compounds is used as a plant virus agent and can well inhibit the tobacco mosaic virus; when used as a bactericide, the compounds have good inhibitory activity on tomato early blight, wheat scab, potato late blight, phytophthora capsici, rape sclerotinia rot, cucumber gray mould, rice sheath blight disease, cucumber fusarium wilt, cercospora brown spot of peanut, apple ring rot, wheat sharp eyespot, corn southern leaf blight, watermelon anthracnose and rice bakanae disease; when used as an insecticide, the compounds have poisonous activity on armyworms, mosquito larvae, cotton bollworms, ostrinia nubilalis, aphids, adult mites and plutella xylostella. In the formula,when molecular nitrogen is not imine, R can represent hydrogen atoms, methyl, acetyl and benzoyl; R and R represent a hydrogen atom or an oxygen atom simultaneously; R and R can represent hydroxyl, acetoxyl, methoxyl, methyleneoxy, a fluorine atom and the hydrogen atom; R is a bromine atom or the fluorine atom; R is the hydrogen atom or vinyl. When nitrogen is imine, R doesnot represent any group; one of R and R does not represent any group, and the other can represent the hydrogen atom, methoxyl, ethyoxyl, benzyloxy and a chlorine atom; R, R, R and Rrepresent the hydrogen atom.

A para-C–H Functionalization of Aniline Derivatives via In situ Generated Bulky Hypervalent Iodinium Reagents

A practical para-C-H functionalization of aniline derivatives has been developed using an in situ generated bulky hypervalent iodinium reagent. Para-iodo, bromo, chloro, nitro, trifluormethyl aniline derivatives can be obtained efficiently, in many cases in 10 min in a transition metal-free manner. Medicinal chemicals or intermediates can be purified without column chromatography or recrystallization, which significantly reduces the waste and simplifies the work-up process.

Metal-Oxidant-Free Cobalt-Catalyzed C(sp2)-H Carbonylation of ortho-Arylanilines: An Approach toward Free (NH)-Phenanthridinones

A traceless directing group assisted Co-catalyzed C(sp2)-H carbonylation of ortho-arylanilines for the synthesis of free (NH)-phenanthridinones in metal-based-oxidant-free fashion was accomplished. This protocol employs diisopropyl azodicarboxylate as the CO source and oxygen as the sole oxidant, and provides good yields with various functional tolerance. The methodology has been applied for the total synthesis of PARP inhibitor PJ-34. Furthermore, the kinetic isotopic effect experiments reveal the C-H bond cleavage probably occurred in the rate-determining step.

Palladium-Catalyzed C-H Activation and Cyclization of Anilides with 2-Iodoacetates and 2-Iodobenzoates: An Efficient Method toward Oxindoles and Phenanthridones

A concise approach to the synthesis of oxindoles and phenanthridones from anilides is described. In the presence of catalytic amount of Pd(OAc)2, 2-iodoacetates and 2-iodobenzoates can be used to functionalize ortho C-H bond of anilides, which subsequently undergo intramolecular cyclization to give the products. A possible reaction mechanism that involves a PdII/PdIV catalytic cycle is proposed with the support of detailed mechanistic studies.

Organic electroluminescent materials and devices

Compounds comprising phosphorescent metal complexes comprising cyclometallated imidazo[1,2-f]phenanthridine and diimidazo[1,2-a:1′,2′-c]quinazoline ligands, or isoelectronic or benzannulated analogs thereof, are described. Organic light emitting diode devices comprising these compounds are also described.

METAL COMPLEXES OF CYCLOMETALLATED IMIDAZO[1,2-f]PHENANTHRIDINE AND DIIMIDAZO[1,2-A:1',2'-C]QUINAZOLINE LIGANDS AND ISOELECTRONIC AND BENZANNULATED ANALOGS THEREOF

The present invention refers to-imidazo [1,2-f] the dee trillion which gets torn phenylphenanthridines and [1,2-a:1 ', 2' -c] quinazoline ligands, or its isoelectronic characteristic and or phosphor including analogue relates to compounds including metal complex. Furthermore, the present invention refers to these compounds including relates organic light emitting diode devices. (by machine translation)

COMPOUND FOR ORGANIC OPTOELECTRONIC DEVICE, ORGANIC LIGHT EMITTING DIODE INCLUDING THE SAME AND DISPLAY INCLUDING THE ORGANIC LIGHT EMITTING DIODE

PURPOSE: A compound for an organic optoelectronic device is provided to manufacture an organic light emitting diode with high light-emitting efficiency under a low driving voltage and ensure excellent lifetime due to superior electrochemical thermal stabi

LIGHT-EMITTING COMPOUND

A phosphorescent compound of formula (I): wherein: M is a transition metal; L in each occurrence is independently a mono- or poly-dentate ligand; R8, R9, R10 and R11 are each independently H or a substituent; D1 and D2 are each independently a dendron; x is at least 1; y is 0 or a positive integer; z1 and z2 are each independently 0 or a positive integer; and n1 and n2 are each independently 0 or 1 with the proviso that at least one of n1 and n2 is 1. The compound may be a phosphorescent compound of an organic light-emitting device.

KOtBu mediated synthesis of phenanthridinones and dibenzoazepinones

Synthesis of substituted phenanthridinones and dibenzoazepinones has been realized from 2-halo-benzamides in the presence of potassium tert-butoxide and a catalytic amount of 1,10-phenanthroline or AIBN. This new carbon-carbon bond forming reaction gives direct access to various biaryl lactams containing six- and seven-membered rings chemoselectively. Carbon-carbon coupling seems to proceed by the generation of a radical in the amide ring which leads to C-H arylation of aniline.