27396-21-0 Usage
Uses
Used in Polymer and Resin Production:
Tert-butyl (4-methoxyphenyl)ethaneperoxoate is used as a radical initiator for the polymerization of monomers in the production of polymers and resins. Its ability to release free radicals upon heating makes it a key component in the synthesis process, contributing to the formation of the desired polymeric materials.
Used in Organic Compound Synthesis:
In the field of organic chemistry, tert-butyl (4-methoxyphenyl)ethaneperoxoate is utilized as a radical initiator in the synthesis of various organic compounds. Its role in generating free radicals upon decomposition facilitates the initiation of reactions that lead to the formation of target organic molecules, making it a valuable tool in organic synthesis processes.
Used in Chemical Industry:
Tert-butyl (4-methoxyphenyl)ethaneperoxoate is employed as a radical initiator in the chemical industry for various applications, including the production of polymers, resins, and organic compounds. Its stability and effectiveness in releasing free radicals upon heating make it a preferred choice for initiating polymerization reactions and other chemical processes.
Check Digit Verification of cas no
The CAS Registry Mumber 27396-21-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,7,3,9 and 6 respectively; the second part has 2 digits, 2 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 27396-21:
(7*2)+(6*7)+(5*3)+(4*9)+(3*6)+(2*2)+(1*1)=130
130 % 10 = 0
So 27396-21-0 is a valid CAS Registry Number.
27396-21-0Relevant academic research and scientific papers
Secondary α-Deuterium Kinetic Isotope Effects Signifying a Polar Transition State in the Thermolysis of Ring-Substituted tert-Butyl Phenylperacetates
Kim, Sung Soo,Tuchkin, Alexey
, p. 3821 - 3824 (2007/10/03)
Several ring-substituted tert-butyl phenylperacetates (YC6H4CH2CO3But) and their deuterated versions (YC6H4CD2CO3But) were prepared (Y: p-OCH3, p-CH3, p-H, and p-NO2). Thermolyses at 80°C in CDCl3 showed excellent first-order kinetics. The rates have been measured as kYH × 104 and kYD × 104 s-1: 11.9 and 9.20 (p-OCH3), 2.64 and 2.22 (p-CH3), 1.06 and 0.93 (p-H), 0.164 and 0.156 (p-NO2). Hammett correlations were derived to yield ρYH+ = -1.17 and ρYD+ = -1.12. However, better Hammett plots were obtained with three points (p-OCH3, p-CH3, and p-H) showing ρYH+ = -1.35 and ρYD+ = -1.28. SDKIE was calculated as 1.293 (p-OCH3), 1.189 (p-CH3), 1.140 (p-H), and 1.051 (p-NO2), showing substantial substituent effects. Values of kYH/kYD for p-NO2 showed little temperature dependence. Hammett correlations and SDKIE were derived from the same kinetic entity that is the bond cleavage.
