2766-64-5Relevant articles and documents
Synthesisandpropertiesof5,7-Dihydropyrido[3,2-b:5,6-b′]diindoles
Hung, Tran Quang,Thang, Ngo Ngoc,Hoang, Do Huy,Dang, Tuan Thanh,Ayub, Khurshid,Villinger, Alexander,Lochbrunner, Stefan,Flechsig, Gerd-Uwe,Langer, Peter
, p. 1007 - 1019 (2015)
5,7-Dihydropyrido[3,2-b:5,6-b]diindoles were prepared by a highly efficient two-step synthesis that involved a site-selective Suzuki coupling reaction of 2,3,5,6-etrabromopyridine and a subsequent Pd-catalyzed cyclization that proceeded through a twofold C-N coupling reaction with aromatic and aliphatic amines. With the exception of the parent molecule, which was described in a patent without any characterization data, the 5,7-dihydropyrido[3,2-b:5,6-b]diindoles are a new chemical entity. Their electrochemical and photochemical properties were investigated. These pyridodiindoles show promising fluorescence properties with good quantum yields and interesting electrochemical behavior. The optical and electronical properties were analyzed and explained by using DFT calculations.
SYNTHESIS OF PHENOXYPYRIDINES UNDER PHASE TRANSFER CATALYSIS CONDITIONS
Abele, E. M.,Gol'dberg, Yu. Sh.,Gavars, M. P.,Gaukhman, A. P.,Shimanskaya, M. V.
, p. 290 - 294 (2007/10/02)
Reactions of halopyridines with alkali metal phenoxides in a two phase liquid-solid catalytic system, rather than in a liquid-liquid phase transfer catalytic system, make it possible to prepare 2-, 3-, and 4-phenoxypyridines from unactivated bromo- or chloropyridines and 2-chloropicolines.In polyhalogenated pyridines only α- and γ-halogen atoms undergo substitution. 7,8-Dibromo-6-azaphenoxane has been prepared by the reaction of 2,3,5,6-tetrabromopyridine with the dipotassium salt of pyrocatechol.