2408-70-0Relevant articles and documents
Synthesis and characterization of highly stable and efficient star-molecules
Huang, Hai-Fang,Xu, Shi-Hua,He, Yan-Bo,Zhu, Cai-Cai,Fan, He-Liang,Zhou, Xue-Hua,Gao, Xi-Cun,Dai, Yan-Feng
, p. 705 - 713 (2013/03/13)
A series of well-defined star-shaped molecules have been synthesized by Pd-catalyzed Suzuki cross-coupling starting from very simple reactants with 1,3,5-trisubstituted benzene, 2,4,6-trisubstituted pyridine and trisubstituted phenylcarbazole as the backbones. These star-molecules are all soluble in common organic solvents and electrochemically stable with reversible cyclic voltammographs and high lying HOMOs. They exhibit excellent blue-fluorescence with quantum yield up to 0.87 and high glass transition temperatures. These molecules offer potential as pure blue-light emitting, hole-transport or host materials for optoelectronic applications.
4,4'-Donor-Substituted and 6,6'-Difunctionalized 2,2'-Bipyridines
Neumann, Uwe,Voegtle, Fritz
, p. 589 - 592 (2007/10/02)
The previously unknown 4,4'-dimethoxy-substituted 6,6'-diacyl-2,2'-bipyridines 7, 8 (acyl = acetyl, formyl) are prepared.Some old procedures in the synthetic sequence were optimized. - Keyword: 2,2'-Bipyridines, building blocks for complex ligands
Continuous process for the production of polybromopyridine compounds
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, (2008/06/13)
A continuous process for producing a polybromopyridine compound comprises admixing a polychloropyridine compound with an anhydrous water soluble solvent in a first reaction zone to form a solution of the polychloropyridine compound. Hydrogen bromide gas is introduced into the solution while maintaining the temperature in the range of from about 70° to about 140° C. to produce a solution of the polybromopyridine compound. The solution is cooled to a temperature in the range of from about 5° to about 35° C. to precipitate the polybromopyridine compound from the anhydrous solvent. The polybromopyridine compound is separated from the anhydrous solvent and the anhydrous solvent is returned to the first reaction zone. Polybromopyridine compounds of increased purity are produced in a process having reduced material, energy and operating costs. The process does not require the use of water or other co-solvents nor the distillation of the reaction product mixture.