276882-72-5Relevant academic research and scientific papers
Total syntheses of the phytotoxic lactones herbarumin I and II and a synthesis-based solution of the pinolidoxin puzzle
Fuerstner, Alois,Radkowski, Karin,Wirtz, Conny,Goddard, Richard,Lehmann, Christian W.,Mynott, Richard
, p. 7061 - 7069 (2002)
A concise approach to a family of potent herbicidal 10-membered lactones is described on the basis of ring-closing metathesis (RCM) as the key step for the formation of the medium-sized ring. This includes the first total syntheses of herbarumin I (1) and
Synthesis of (-)-pinolidoxin: Divergent synthetic strategy exploiting a common silacyclic precursor
Liu, Dong,Kozmin, Sergey A.
, p. 3005 - 3007 (2007/10/03)
(figure presented) We describe a highly convergent and efficient synthesis of (-)-pinolidoxin, a potent modulator of plant pathogenesis, providing unambiguous determination of the relative and absolute stereostructure of this highly oxygenated fungal meta
