27899-45-2

Basic information

• Product Name: 3,3-dimethylbicyclo[2.2.1]heptane-2-methanol
• Synonyms: 3,3-dimethylbicyclo[2.2.1]heptane-2-methanol;Einecs 248-719-0
• CAS NO: 27899-45-2
• Molecular Formula: C₁₀H₁₈O
• Molecular Weight: 154.24932
• EINECS: 248-719-0
• Mol File: 27899-45-2.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 219.5°Cat760mmHg
• Flash Point: 96°C
• Appearance: /
• Density: 0.95g/cm³
• CAS DataBase Reference: 3,3-dimethylbicyclo[2.2.1]heptane-2-methanol(CAS DataBase Reference)
• NIST Chemistry Reference: 3,3-dimethylbicyclo[2.2.1]heptane-2-methanol(27899-45-2)
• EPA Substance Registry System: 3,3-dimethylbicyclo[2.2.1]heptane-2-methanol(27899-45-2)

Safety Data

• Hazardous Substances Data: 27899-45-2(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H18O/c1-10(2)8-4-3-7(5-8)9(10)6-11/h7-9,11H,3-6H2,1-2H3

Upstream product

• 472-17-3 (1S,4R)-3,3-Dimethyl-bicyclo[2.2.1]heptane-2-carbaldehyde 
• 64-17-5 ethanol 
• 50705-16-3 3,3-dimethylbicyclo[2.2.1]heptane-2-carbaldehyde 
• 20440-73-7 (+/-)-2,2-dimethyl-3-((Ξ)-nitromethylene)-norbornane of mp: 65 degree 
• 64-19-7 acetic acid 
• 5056-10-0 acetic acid-(3,3-dimethyl-[2]norbornylidenemethyl ester) 
• 67519-00-0 2-exo-10-camphanoic acid 
• 875-03-6 (+/-)-camphene oxide 
• 85506-67-8 endo-2,2-dimethylbicyclo<2.2.1>heptane-3-carboxylic acid 
• 565-00-4 dl-camphene 
• 79-92-5 camphene 
• 875-03-6 3,3-dimethyl-spiro[norbornan-2,2'-oxirane] 
• 542-92-7 cyclopenta-1,3-diene 
• 15780-34-4 1-(3,3-Dimethyl-bicyclo<2.2.1>hept-2-yl)ethanon 

Downstream Products

• 50705-16-3 3,3-dimethylbicyclo[2.2.1]heptane-2-carbaldehyde 
• 94200-95-0 1-(3,3-Dimethyl-bicyclo<2.2.1>hept-2-yl)-2-methyl-propan-2-ol 
• 2226-08-6 2-(3,3-Dimethyl-bicyclo<2.2.1>hept-2-yl)-ethanol 

Relevant articles and documents

A General Regioselective Synthesis of Alcohols by Cobalt-Catalyzed Hydrogenation of Epoxides

A straightforward methodology for the synthesis of anti-Markovnikov-type alcohols is presented. By using a specific cobalt triphos complex in the presence of Zn(OTf)2 as an additive, the hydrogenation of epoxides proceeds with high yields and selectivities. The described protocol shows a broad substrate scope, including multi-substituted internal and terminal epoxides, as well as a good functional-group tolerance. Various natural-product derivatives, including steroids, terpenoids, and sesquiterpenoids, gave access to the corresponding alcohols in moderate-to-excellent yields.

Novel Reduction of Carboxylic Acids and Hydroboration of Olefins by Electrolysis of Sodium Borohydride

Electrochemical oxidation of sodium borohydride in diglyme containing aliphatic or aromatic carboxylic acids followed by acid-catalyzed hydrolysis afforded the corresponding primary alcohols in good yields.Furthermore, similar electrochemical oxidation in the presence of a variety of olefins instead of carboxylic acids, followed by treatment with alkaline-hydrogen peroxide, brought about novel electrochemical hydroboration to give the corresponding alcohols regio- and stereoselectively in good yields.

Oxygenation of Oleefinic Hydrocarbons Catalyzed by Iron(II) Acetonitrile Solvate

Oxygenation reactions of olefins having an endo- or exo-cyclic double bond, namely, cyclohexene, norbornene, camphene, longifolene, and ent-kaurene, with a simple model reagent, Fe(MeCN)62+-H2O2-Ac2O, for mono-oxygenase were investigated in connection with their biotransformations.Keywords oxygenation; olefin; endo-cyclic double bond; exo-cyclic double bond; iron(II) acetonitrile solvate; hydrogen peroxide; model enzyme; mono-oxygenase