27991-58-8Relevant articles and documents
COMPLEX COMPOUND, AND PRODUCTION METHOD OF SILOXANE
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Paragraph 0046; 0047, (2019/07/13)
PROBLEM TO BE SOLVED: To provide a production method of siloxane capable of producing siloxane efficiently; and to provide a compound useful in production of siloxane. SOLUTION: In a method, siloxane is produced efficiently, by progressing a dehydrogenati
Aerobic Co or Cu/NHPI-catalyzed oxidation of hydride siloxanes: Synthesis of siloxanols
Arzumanyan, Ashot V.,Goncharova, Irina K.,Novikov, Roman A.,Milenin, Sergey A.,Boldyrev, Konstantin L.,Solyev, Pavel N.,Tkachev, Yaroslav V.,Volodin, Alexander D.,Smol'Yakov, Alexander F.,Korlyukov, Alexander A.,Muzafarov, Aziz M.
, p. 1467 - 1471 (2018/04/12)
A highly efficient preparative method for the synthesis of siloxanols based on aerobic Co(OAc)2 or Cu(OAc)2/NHPI-catalyzed oxidation of hydride siloxanes using "green", commercially available, simple inexpensive reagents and mild reaction conditions has been proposed. This is a general reaction for the synthesis of mono-, oligo- and polymeric siloxanols with various structures (linear, branched and cyclic).
Method of manufacturing polyimidesiloxane compd. (by machine translation)
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Paragraph 0027; 0028, (2016/11/17)
PROBLEM TO BE SOLVED: rhodium, platinum, and palladium complex or the like instead of the catalyst is found, to provide a new method for manufacturing polyimidesiloxane compd. ~~~ a SOLUTION: and in the condensation reaction silanolated hydrosilane, nickel compound represented by the following eq. (C) is used as a catalyst, siloxane compound can be produced. [And 1] ( In the formula, R 3 are each independently a hydrogen atom, or a nitrogen atom, an oxygen atom, a sulfur atom, a silicon atom, phosphorus atom, and a halogen atom is selected from the group consisting of at least 1 may also include a kind of carbon number 1-20 hydrocarbon group. ) Selected drawing: no (by machine translation)