27991-58-8

Upstream product

• 823207-19-8 1-chloro-3,3,3-trimethyl-1-phenyl-disiloxane 
• 75-77-4 chloro-trimethyl-silane 
• 1066-35-9 dimethylmonochlorosilane 
• 1631-84-1 dichlorophenylsilane 
• 1066-40-6 Trimethylsilanol 
• 694-53-1 phenylsilane 
• 108-90-7 chlorobenzene 

Downstream Products

• 221472-10-2 3-aminopropyl-bis(trimethylsiloxy)phenylsilane 
• 18758-91-3 1,1,1,7,7,7-hexamethyl-3,5-diphenyl-3,5-bis(trimethylsiloxy)tetrasiloxane 
• 24082-16-4 C₁₂H₂₃ClO₂Si₃ 

Relevant academic research and scientific papers

COMPLEX COMPOUND, AND PRODUCTION METHOD OF SILOXANE

PROBLEM TO BE SOLVED: To provide a production method of siloxane capable of producing siloxane efficiently; and to provide a compound useful in production of siloxane. SOLUTION: In a method, siloxane is produced efficiently, by progressing a dehydrogenati

Aerobic Co or Cu/NHPI-catalyzed oxidation of hydride siloxanes: Synthesis of siloxanols

A highly efficient preparative method for the synthesis of siloxanols based on aerobic Co(OAc)2 or Cu(OAc)2/NHPI-catalyzed oxidation of hydride siloxanes using "green", commercially available, simple inexpensive reagents and mild reaction conditions has been proposed. This is a general reaction for the synthesis of mono-, oligo- and polymeric siloxanols with various structures (linear, branched and cyclic).

Selective hydrosiloxane synthesis: Via dehydrogenative coupling of silanols with hydrosilanes catalysed by Fe complexes bearing a tetradentate PNNP ligand

A well-defined iron complex system was established using PNNP-R (R = Ph and Cy) as a strong σ-donating ligand with a rigid meridional tetradentate structure. Reactive Fe(0) complexes [{Fe(PNNP-R)}2(μ-N2)] were synthesized by a reaction of the corresponding iron dihalide with NaBEt3H and structurally characterized. The reaction proceeded via the iron dihydride intermediate [Fe(H)2(PNNP-R)], which underwent H2 reductive elimination, supporting the hemilabile behavior of PNNP-R. [{Fe(PNNP-R)}2(μ-N2)] catalyzed the dehydrogenative coupling of silanols with silanes to selectively form various hydrosiloxanes, which are important building blocks for the synthesis of a range of siloxane compounds. This system exhibited higher catalytic efficiency than the previously reported precious-metal-catalyzed systems.

Highly Selective Synthesis of Hydrosiloxanes by Au-Catalyzed Dehydrogenative Cross-Coupling Reaction of Silanols with Hydrosilanes

We report a highly selective synthesis of siloxane building blocks containing SiH2 or SiH functionalities. AuCl(PPh3)/PPh3 or AuCl(PPh3)/PnBu3 system catalyzed the reaction of trihydrosilanes with silanols giving SiH2-containing siloxanes exclusively. On the other hand, a highly selective reaction of dihydrosilanes with silanols to afford SiH-containing siloxanes was achieved by simply changing the phosphine ligand to a bidentate one, xantphos. Usefulness of SiH2-containing siloxanes was demonstrated by the synthesis of a trisiloxane, Et3SiOSi(Ph)(H)OSitBuMe2, and a pentasiloxane, Ph2Si(OSiHPhOSiEt3)2, bearing SiH functionalities.

Method of manufacturing polyimidesiloxane compd. (by machine translation)

PROBLEM TO BE SOLVED: rhodium, platinum, and palladium complex or the like instead of the catalyst is found, to provide a new method for manufacturing polyimidesiloxane compd. ~~~ a SOLUTION: and in the condensation reaction silanolated hydrosilane, nickel compound represented by the following eq. (C) is used as a catalyst, siloxane compound can be produced. [And 1] ( In the formula, R 3 are each independently a hydrogen atom, or a nitrogen atom, an oxygen atom, a sulfur atom, a silicon atom, phosphorus atom, and a halogen atom is selected from the group consisting of at least 1 may also include a kind of carbon number 1-20 hydrocarbon group. ) Selected drawing: no (by machine translation)

Substituted lithiumtrimethylsiloxysilanides LiSiRR′(OSiMe3) - Investigations of their synthesis, stability and reactivity

The reactions of the trimethylsiloxychlorosilanes (Me3SiO)RR′SiCl (1a-h: R′ = Ph, 1a: R = H, 1b: R = Me, 1c: R = Et, 1d: R = iPr, 1e: R = tBu, 1f: R = Ph, 1g: R = 2,4,6-Me3C6H2 (Mes), 1h: R